FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2746017557> ?p ?o ?g. }

• W2746017557 endingPage "126" @default.
• W2746017557 startingPage "118" @default.
• W2746017557 abstract "Abstract 6-Aminouracils have extensively been used as precursors for synthesizing numerous uracil derivatives of biological and pharmaceutical significance. This study describes an application of 1,3-dimethyl-5-(arylazo)-6-aminouracils (Uazo: Uazo1-Uazo4, precursors) for an efficient synthesis of a series of 8-substituted-azapurins (AP), namely 1,3-dimethyl-8-(aryl)-azapurin-2,6-diones (aryl = p-HC6H4 (AP1), -MeC6H4 (AP2), ClC6H4 (AP3), and SO2NH2C6H4 (AP4)) following an oxidation method in the presence of copper (II) nitrate and in alkaline medium. The obtained compounds were isolated in good yields as crystalline air-stable products and have been fully characterized in the solution by UV–vis and NMR spectroscopy, as well as in the solid state by FT-IR spectroscopy, elemental analysis, and single-crystal X-ray diffraction (for AP2 and AP4). UV–vis study evidences that the conversion of the 6-aminouracil precursors occurs via an intermediate, Cu(II)-complex and a plausible mechanism for the formation of AP1-AP4 has been proposed. Unlike AP2 the crystal structure of AP4 reveals the formation of interdigitated 1D H-bonded chains that has been topologically classified within the 2C1 type. The 1H NMR spectra of the products have proton signals that completely devoid of hydrazone ( NH ) and imine (=NH) signals of their parent Uazo derivatives, thus confirming their full conversion and a stability of the AP1-AP4 in solution. The excitation and emission spectra of AP1-AP4 were also recorded in solution, revealing electronic transitions between similar vibrational energy levels of S0 (singlet ground state) and S1 (singlet first excited state)." @default.
• W2746017557 created "2017-08-31" @default.
• W2746017557 creator A5008626158 @default.
• W2746017557 creator A5011021117 @default.
• W2746017557 creator A5022002358 @default.
• W2746017557 creator A5023489988 @default.
• W2746017557 creator A5036983428 @default.
• W2746017557 date "2017-12-01" @default.
• W2746017557 modified "2023-10-16" @default.
• W2746017557 title "Study of an efficient conversion of 1,3-dimethyl-5-(Arylazo)-6-Amino-Uracils to 1,3-dimethyl-8-(Aryl)-Azapurin-2,6-Diones" @default.
• W2746017557 cites W1151769068 @default.
• W2746017557 cites W1618577459 @default.
• W2746017557 cites W1969603712 @default.
• W2746017557 cites W1971026425 @default.
• W2746017557 cites W1972258799 @default.
• W2746017557 cites W1979749286 @default.
• W2746017557 cites W1984192623 @default.
• W2746017557 cites W1991166536 @default.
• W2746017557 cites W1992304492 @default.
• W2746017557 cites W1993047166 @default.
• W2746017557 cites W1995837371 @default.
• W2746017557 cites W1999042745 @default.
• W2746017557 cites W1999675360 @default.
• W2746017557 cites W1999958374 @default.
• W2746017557 cites W2002588343 @default.
• W2746017557 cites W2008462901 @default.
• W2746017557 cites W2015052655 @default.
• W2746017557 cites W2015139317 @default.
• W2746017557 cites W2023887340 @default.
• W2746017557 cites W2026703501 @default.
• W2746017557 cites W2027297029 @default.
• W2746017557 cites W2034320943 @default.
• W2746017557 cites W2041410825 @default.
• W2746017557 cites W2042110543 @default.
• W2746017557 cites W2054219815 @default.
• W2746017557 cites W2057542816 @default.
• W2746017557 cites W2058877183 @default.
• W2746017557 cites W2063820454 @default.
• W2746017557 cites W2064322299 @default.
• W2746017557 cites W2071291732 @default.
• W2746017557 cites W2084682658 @default.
• W2746017557 cites W2094378252 @default.
• W2746017557 cites W2095329186 @default.
• W2746017557 cites W2102629214 @default.
• W2746017557 cites W2136231406 @default.
• W2746017557 cites W2144569337 @default.
• W2746017557 cites W2146886080 @default.
• W2746017557 cites W2158709750 @default.
• W2746017557 cites W2312875904 @default.
• W2746017557 cites W2314656511 @default.
• W2746017557 cites W2321018027 @default.
• W2746017557 cites W2324639631 @default.
• W2746017557 cites W2328906361 @default.
• W2746017557 cites W2329223767 @default.
• W2746017557 cites W2337656357 @default.
• W2746017557 cites W2338050358 @default.
• W2746017557 cites W2345885499 @default.
• W2746017557 cites W2522378937 @default.
• W2746017557 cites W2594609824 @default.
• W2746017557 cites W2598908782 @default.
• W2746017557 cites W2949138590 @default.
• W2746017557 cites W3137259968 @default.
• W2746017557 cites W39496332 @default.
• W2746017557 cites W2070097556 @default.
• W2746017557 cites W2314390903 @default.
• W2746017557 doi "https://doi.org/10.1016/j.molstruc.2017.08.087" @default.
• W2746017557 hasPublicationYear "2017" @default.
• W2746017557 type Work @default.
• W2746017557 sameAs 2746017557 @default.
• W2746017557 citedByCount "5" @default.
• W2746017557 countsByYear W27460175572019 @default.
• W2746017557 countsByYear W27460175572020 @default.
• W2746017557 countsByYear W27460175572021 @default.
• W2746017557 countsByYear W27460175572022 @default.
• W2746017557 countsByYear W27460175572023 @default.
• W2746017557 crossrefType "journal-article" @default.
• W2746017557 hasAuthorship W2746017557A5008626158 @default.
• W2746017557 hasAuthorship W2746017557A5011021117 @default.
• W2746017557 hasAuthorship W2746017557A5022002358 @default.
• W2746017557 hasAuthorship W2746017557A5023489988 @default.
• W2746017557 hasAuthorship W2746017557A5036983428 @default.
• W2746017557 hasConcept C155647269 @default.
• W2746017557 hasConcept C178790620 @default.
• W2746017557 hasConcept C185592680 @default.
• W2746017557 hasConcept C2780263894 @default.
• W2746017557 hasConcept C2781076698 @default.
• W2746017557 hasConceptScore W2746017557C155647269 @default.
• W2746017557 hasConceptScore W2746017557C178790620 @default.
• W2746017557 hasConceptScore W2746017557C185592680 @default.
• W2746017557 hasConceptScore W2746017557C2780263894 @default.
• W2746017557 hasConceptScore W2746017557C2781076698 @default.
• W2746017557 hasFunder F4320334779 @default.
• W2746017557 hasLocation W27460175571 @default.
• W2746017557 hasOpenAccess W2746017557 @default.
• W2746017557 hasPrimaryLocation W27460175571 @default.
• W2746017557 hasRelatedWork W2021219953 @default.
• W2746017557 hasRelatedWork W2075559805 @default.
• W2746017557 hasRelatedWork W2094190383 @default.

• next