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- W2746982550 abstract "Higher dielectric constant, lower dielectric loss and better frequency stability have been the developing trends for high dielectric constant (high-k) materials. Herein, new composites have been developed through building unique structure by using hyperbranched polysiloxane modified 3D-barium titanate foam (BTF) ([email protected]) as the functional fillers and phenolphthalein poly(ether sulfone) (cPES)/cyanate ester (CE) blend as the resin matrix. For [email protected]/cPES/CE composite with 34.1 vol% BTF, its dielectric constant at 100 Hz is as high as 162 and dielectric loss is only 0.007; moreover, the dielectric properties of [email protected]/cPES/CE composites exhibit excellent frequency stability. To reveal the mechanism behind these attractive performances of [email protected]/cPES/CE composites, three kinds of composites (BTF/CE, BTF/cPES/CE, [email protected]/CE) were prepared, their structure and integrated performances were intensively investigated and compared with those of [email protected]/cPES/CE composites. Results show that the surface modification of BTF is good for preparing composites with improved thermal stability; while introducing flexible cPES to CE is beneficial to fabricate composites with good quality through effectively blocking cracks caused by the stress concentration, and then endowing the composites with good dielectric properties at reduced concentration of ceramics." @default.
- W2746982550 created "2017-08-31" @default.
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- W2746982550 date "2018-01-01" @default.
- W2746982550 modified "2023-10-16" @default.
- W2746982550 title "High-k 3D-barium titanate foam/phenolphthalein poly(ether sulfone)/cyanate ester composites with frequency-stable dielectric properties and extremely low dielectric loss under reduced concentration of ceramics" @default.
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- W2746982550 doi "https://doi.org/10.1016/j.apsusc.2017.08.119" @default.
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