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- W2747261710 abstract "Catalytic efficiencies of eight primary amine-based palladium(II) complexes of general formula, trans-[PdCl2(RNH2)2] (1L1-L8), have been evaluated for the Suzuki-Miyaura reaction of 4-bromonitrobenzene with phenylboronic acid at room temperature in water. The efficiencies of the catalysts follow the order: Ph3CNH2 (L8) > Ph2CHNH2 (L7) > Ph2CH2NH2 (L6) > BuNH2 (L4) > CyNH2 (L5) > PrNH2 (L2) > BuNH2 (L3) > PrNH2 (L1). In order to ascertain the parameters affecting catalytic efficiencies, DFT based reactivity descriptors have been analyzed for the ligands. Good linear correlation is obtained between the observed yield (%) and the gas phase reactivity descriptors (chemical hardness, chemical potential and electrophilicity index). Good-to-excellent yields of coupling products are achieved using the 1L8 complex as the catalyst for a range of aryl halides." @default.
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- W2747261710 date "2012-11-01" @default.
- W2747261710 modified "2023-09-23" @default.
- W2747261710 title "Primary amine-based palladium(II) complexes as catalysts for Suzuki-Miyaura reaction: Experimental and theoretical investigations on the effects of substituents on nitrogen atom" @default.
- W2747261710 hasPublicationYear "2012" @default.
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