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• W2747520506 endingPage "502" @default.
• W2747520506 startingPage "495" @default.
• W2747520506 abstract "Diffusive isotope fractionation of organic compounds in aqueous solution was investigated by means of liquid-liquid and liquid-gas partitioning experiments under kinetic control. The two-film model was used to describe phase-transfer kinetics. It assumes the diffusion of solutes across a stagnant water boundary layer as the rate-controlling step. For all investigated solutes (benzene-D0 and -D6, toluene-D0, -D5, and -D8, cyclohexane-D0 and -D12), there was no significant observable fractionation effect between nondeuterated and perdeuterated isotopologues, resulting in a ratio of diffusion coefficients Dlight: Dheavy = 1.00 ± 0.01. In addition, isotope fractionation due to equilibrium partitioning of solutes between water and n-octane or gas phase was measured. The deuterated compounds are more hydrophilic than their light isotopologues in all cases, giving rise to fractionation coefficients αHpart = Koctane/water,H: Koctane/water,D = 1.085 to 1.15. Thus, thermodynamic fractionation effects are much larger than diffusion fractionation effects. Methodical and environmental implications of these findings are discussed." @default.
• W2747520506 created "2017-08-31" @default.
• W2747520506 creator A5041145302 @default.
• W2747520506 creator A5047298290 @default.
• W2747520506 creator A5063060059 @default.
• W2747520506 date "2018-01-01" @default.
• W2747520506 modified "2023-10-14" @default.
• W2747520506 title "Isotope fractionation in phase-transfer processes under thermodynamic and kinetic control – Implications for diffusive fractionation in aqueous solution" @default.
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• W2747520506 doi "https://doi.org/10.1016/j.scitotenv.2017.08.063" @default.
• W2747520506 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28820980" @default.
• W2747520506 hasPublicationYear "2018" @default.
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