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- W2747634712 abstract "Three new complexes [Co(N3Py2)(H2O)](ClO4)2 1, [Ni(N3Py2)(H2O)](ClO4)2 2 and [Cu(N3Py2)](ClO4)2 3 (N3Py2 is N,N′-dimethyl-N-(2-(methyl(pyridin-2-ylmethyl)amino)ethyl)-N′-(pyridin-2-ylmethyl)ethane-1,2-diamine) have been synthesized and characterized. Non-heme ligand N3Py2 have been prepared by Eschweiler-Clarke method and reported for the first time. Compounds 1 and 2 were characterized by single crystal X-ray structure analysis. The structure of 1 and 2 revealed that Co(II) cation in 1 and Ni(II) cation in 2 are bonded to the five nitrogen atoms of N3Py2 and a water molecule thus forming an octahedral motif [M(N3Py2)(H2O)]2+. For compound 3, a square pyramidal geometry has been proposed based on the spectroscopic, elemental analysis and ESI-MS data. Compounds 1–3 were tested as catalysts in the oxidation of cumene and adamantane using m-CPBA. Comparative effect of counter anions on the product yields was observed when the perchlorates anions of 1–3 were replaced with tetraphenylborates to give compounds 1a–3a. The turnover numbers of alcohol over ketone product increased in order of catalysts, 1(1a) > 2(2a) > 3(3a)." @default.
- W2747634712 created "2017-08-31" @default.
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- W2747634712 date "2017-10-01" @default.
- W2747634712 modified "2023-09-24" @default.
- W2747634712 title "Synthesis and characterization of N3Py2 ligand-based cobalt(II), nickel(II) and copper(II) catalysts for efficient conversion of hydrocarbons to alcohols" @default.
- W2747634712 cites W1107552735 @default.
- W2747634712 cites W1887089892 @default.
- W2747634712 cites W1965427515 @default.
- W2747634712 cites W1967700647 @default.
- W2747634712 cites W1972512120 @default.
- W2747634712 cites W1976715301 @default.
- W2747634712 cites W1979233692 @default.
- W2747634712 cites W1979609198 @default.
- W2747634712 cites W1981704948 @default.
- W2747634712 cites W1983897992 @default.
- W2747634712 cites W1984640061 @default.
- W2747634712 cites W1986706010 @default.
- W2747634712 cites W1990949304 @default.
- W2747634712 cites W1991374426 @default.
- W2747634712 cites W1992089583 @default.
- W2747634712 cites W1996641105 @default.
- W2747634712 cites W1997043147 @default.
- W2747634712 cites W2002305669 @default.
- W2747634712 cites W2002999900 @default.
- W2747634712 cites W2005449162 @default.
- W2747634712 cites W2007547727 @default.
- W2747634712 cites W2013945680 @default.
- W2747634712 cites W2015776744 @default.
- W2747634712 cites W2019948883 @default.
- W2747634712 cites W2023558950 @default.
- W2747634712 cites W2025798565 @default.
- W2747634712 cites W2029442289 @default.
- W2747634712 cites W2032746505 @default.
- W2747634712 cites W2034672440 @default.
- W2747634712 cites W2038700747 @default.
- W2747634712 cites W2040299058 @default.
- W2747634712 cites W2042168356 @default.
- W2747634712 cites W2043915273 @default.
- W2747634712 cites W2049474126 @default.
- W2747634712 cites W2050617599 @default.
- W2747634712 cites W2051346747 @default.
- W2747634712 cites W2052759017 @default.
- W2747634712 cites W2057331738 @default.
- W2747634712 cites W2058440922 @default.
- W2747634712 cites W2061332485 @default.
- W2747634712 cites W2062266555 @default.
- W2747634712 cites W2062847668 @default.
- W2747634712 cites W2063743169 @default.
- W2747634712 cites W2064729225 @default.
- W2747634712 cites W2067670037 @default.
- W2747634712 cites W2073274705 @default.
- W2747634712 cites W2074274746 @default.
- W2747634712 cites W2074600940 @default.
- W2747634712 cites W2075857656 @default.
- W2747634712 cites W2078695517 @default.
- W2747634712 cites W2104576511 @default.
- W2747634712 cites W2105089028 @default.
- W2747634712 cites W2107830496 @default.
- W2747634712 cites W2121061700 @default.
- W2747634712 cites W2125148470 @default.
- W2747634712 cites W2131350133 @default.
- W2747634712 cites W2145249115 @default.
- W2747634712 cites W2151011742 @default.
- W2747634712 cites W2151130802 @default.
- W2747634712 cites W2156732153 @default.
- W2747634712 cites W2157970687 @default.
- W2747634712 cites W2159063344 @default.
- W2747634712 cites W2226953743 @default.
- W2747634712 cites W2291793443 @default.
- W2747634712 cites W2312736635 @default.
- W2747634712 cites W2314103148 @default.
- W2747634712 cites W2330913721 @default.
- W2747634712 cites W2417938186 @default.
- W2747634712 cites W2509897495 @default.
- W2747634712 cites W2518909640 @default.
- W2747634712 cites W2530635218 @default.
- W2747634712 cites W2559682900 @default.
- W2747634712 cites W2598146353 @default.
- W2747634712 cites W2951087944 @default.
- W2747634712 cites W2952891508 @default.
- W2747634712 cites W3138313704 @default.
- W2747634712 cites W340667313 @default.
- W2747634712 doi "https://doi.org/10.1016/j.ica.2017.08.027" @default.
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