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- W2748014715 abstract "It is for me a great pleasure to be here and to have the privilege of opening this first international meeting of workers in the flourishing new field of photoelectron spectroscopy. It is a special pleasure to be able to meet here with the pioneers of the field, in particular Dr Turner, Professor Price, and Professor McDowell, who have worked with ultraviolet photons, and Professor Siegbahn who has worked mainly with X-rays. Photoelectron spectroscopy has already shown, and will continue to show, unique ability to see down into the depths of molecules. It has given a new reality to the idea of molecular orbitals, by determining quantitative values for their binding energies, and also by giving information about their bonding characteristics. Strictly speaking, molecular orbitals are no more than convenient theoretical building blocks for approximate descriptions of the electronic structures of molecules. When we speak of the binding energy, or the orbital energy, of a molecular orbital, the actual physical reality is an ionization energy , that is to say, the energy required to create a stationary state of the positive ion of a molecule by removing one electron from that molecule. In general, these are excited states of the molecular ion. However, the molecular ion states which are disclosed by photoelectron spectroscopy correspond, for the most part at least, to the removal of an electron from a particular molecular orbital." @default.
- W2748014715 created "2017-08-31" @default.
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- W2748014715 date "1970-11-05" @default.
- W2748014715 modified "2023-09-27" @default.
- W2748014715 title "A Discussion on photoelectron spectroscopy - Introductory remarks" @default.
- W2748014715 doi "https://doi.org/10.1098/rsta.1970.0058" @default.
- W2748014715 hasPublicationYear "1970" @default.
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