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• W2748067054 abstract "The molybdenum and tungsten 2,4,6-trimethylbenzylidyne complexes [MesC≡M{OC(CF3)nMe3–n}3] (M = Mo: MoF0, n = 0; MoF3, n = 1; MoF6, n = 2; MoF9, n = 3; M = W: WF3, n = 1; Mes = 2,4,6-trimethylphenyl) were prepared by the reaction of the tribromides [MesC≡MBr3(dme)] (dme = 1,2-dimethoxyethane) with the corresponding potassium alkoxides KOC(CF3)nMe3–n. The molecular structures of all complexes were established by X-ray diffraction analysis. The catalytic activity of the resulting alkylidyne complexes in the homometathesis and ring-closing alkyne metathesis of internal and terminal alkynes was studied, revealing a strong dependency on the fluorine content of the alkoxide ligand. The different catalytic performances were rationalized by DFT calculations involving the metathesis model reaction of 2-butyne. Because the calculations predict the stabilization of metallacyclobutadiene (MCBD) intermediates by increasing the degree of fluorination, MoF9 was treated with 3-hexyne to afford the MCBD complex [(C3Et3)Mo{OC(CF3)3}3], which was characterized spectroscopically." @default.
• W2748067054 created "2017-08-31" @default.
• W2748067054 creator A5002455973 @default.
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• W2748067054 creator A5047299792 @default.
• W2748067054 date "2017-08-24" @default.
• W2748067054 modified "2023-09-30" @default.
• W2748067054 title "Tuning the Catalytic Alkyne Metathesis Activity of Molybdenum and Tungsten 2,4,6-Trimethylbenzylidyne Complexes with Fluoroalkoxide Ligands OC(CF₃)_<i>n</i>Me_3–<i>n</i> (<i>n</i> = 0–3)" @default.
• W2748067054 cites W1945538030 @default.
• W2748067054 cites W1970071140 @default.
• W2748067054 cites W1972756549 @default.
• W2748067054 cites W1973898708 @default.
• W2748067054 cites W1975040572 @default.
• W2748067054 cites W1988069477 @default.
• W2748067054 cites W1990492750 @default.
• W2748067054 cites W2006332185 @default.
• W2748067054 cites W2009409892 @default.
• W2748067054 cites W2016504200 @default.
• W2748067054 cites W2030200736 @default.
• W2748067054 cites W2030340979 @default.
• W2748067054 cites W2034030823 @default.
• W2748067054 cites W2035849372 @default.
• W2748067054 cites W2037886348 @default.
• W2748067054 cites W2038662926 @default.
• W2748067054 cites W2039969031 @default.
• W2748067054 cites W2040500306 @default.
• W2748067054 cites W2050212164 @default.
• W2748067054 cites W2057319521 @default.
• W2748067054 cites W2058029493 @default.
• W2748067054 cites W2061506098 @default.
• W2748067054 cites W2062716053 @default.
• W2748067054 cites W2063440454 @default.
• W2748067054 cites W2063973613 @default.
• W2748067054 cites W2066303397 @default.
• W2748067054 cites W2069308676 @default.
• W2748067054 cites W2070576812 @default.
• W2748067054 cites W2070932217 @default.
• W2748067054 cites W2074736496 @default.
• W2748067054 cites W2077204658 @default.
• W2748067054 cites W2082275305 @default.
• W2748067054 cites W2084592553 @default.
• W2748067054 cites W2084859712 @default.
• W2748067054 cites W2086591041 @default.
• W2748067054 cites W2097581046 @default.
• W2748067054 cites W2103376749 @default.
• W2748067054 cites W2106181410 @default.
• W2748067054 cites W2106182782 @default.
• W2748067054 cites W2106733815 @default.
• W2748067054 cites W2107441349 @default.
• W2748067054 cites W2115035500 @default.
• W2748067054 cites W2116976632 @default.
• W2748067054 cites W2119514011 @default.
• W2748067054 cites W2120892357 @default.
• W2748067054 cites W2121356735 @default.
• W2748067054 cites W2131514869 @default.
• W2748067054 cites W2139326169 @default.
• W2748067054 cites W2143981217 @default.
• W2748067054 cites W2145161264 @default.
• W2748067054 cites W2146908689 @default.
• W2748067054 cites W2148284063 @default.
• W2748067054 cites W2149157268 @default.
• W2748067054 cites W2149549149 @default.
• W2748067054 cites W2151937146 @default.
• W2748067054 cites W2153941652 @default.
• W2748067054 cites W2160996704 @default.
• W2748067054 cites W2162135671 @default.
• W2748067054 cites W2171984811 @default.
• W2748067054 cites W2175802197 @default.
• W2748067054 cites W2192272844 @default.
• W2748067054 cites W2221968149 @default.
• W2748067054 cites W2257684812 @default.
• W2748067054 cites W2268529182 @default.
• W2748067054 cites W2316527413 @default.
• W2748067054 cites W2332286668 @default.
• W2748067054 cites W2339587248 @default.
• W2748067054 cites W2342397295 @default.
• W2748067054 cites W2343129581 @default.
• W2748067054 cites W2343916378 @default.
• W2748067054 cites W2345550551 @default.
• W2748067054 cites W2416423084 @default.
• W2748067054 cites W2473813983 @default.
• W2748067054 cites W2496324209 @default.
• W2748067054 cites W2508149037 @default.
• W2748067054 cites W2594079414 @default.
• W2748067054 cites W2594972303 @default.
• W2748067054 cites W2615786680 @default.
• W2748067054 cites W2762068382 @default.
• W2748067054 cites W2952327909 @default.
• W2748067054 cites W3004763264 @default.
• W2748067054 cites W4236715230 @default.
• W2748067054 cites W4243338209 @default.
• W2748067054 doi "https://doi.org/10.1021/acs.organomet.7b00519" @default.
• W2748067054 hasPublicationYear "2017" @default.
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