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- W2748908045 abstract "The reactions of the monomeric phosphanylboranes Ph 2 P–BH 2 · NMe 3 ( 1a ) and t BuHP–BH 2 · NMe 3 ( 1b ) with the main group Lewis acids BH 3 and BBr 3 yield the adducts H 3 B · Ph 2 P–BH 2 · NMe 3 ( 2a ) and H 3 B · t BuHP–BH 2 · NMe 3 ( 2b ), Br 3 B · Ph 2 P–BH 2 · NMe 3 ( 3a ), and Br 3 B · t BuHP–BH 2 · NMe 3 ( 3b ). All these compounds were completely characterized by single‐crystal X‐ray structure analysis, NMR and IR spectroscopy as well as mass spectrometry and DFT computations. The secondary and tertiary phosphines 1a and 1b behave as classical Lewis bases to coordinate B X 3 ( X = H, Br) as terminal groups." @default.
- W2748908045 created "2017-08-31" @default.
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- W2748908045 date "2017-08-16" @default.
- W2748908045 modified "2023-10-10" @default.
- W2748908045 title "Coordination of Boron‐centered Lewis Acids by <i>organo</i>‐substituted Phosphanylboranes" @default.
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- W2748908045 doi "https://doi.org/10.1002/zaac.201700219" @default.
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