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• W2748921036 abstract "An in situ synthesis of a new nanocomposite, polyaniline/manganese dioxide/titanium dioxide (PANI/MnO2/TiO2), via a one-pot oxidative polymerization method at room temperature is described in this article. The characterization was done on the synthesized nanocomposite using UV–vis, FT-IR, XRD, TGA, SEM, and TEM analysis. A superior catalytic activity is exhibited by the synergistic PANI/MnO2/TiO2 nanocomposite in the conversion of toxic Cr6+ to benign Cr3+ in comparison with PANI, MnO2, TiO2, PANI/MnO2, PANI/TiO2, MnO2/TiO2, and other nanocomposite materials reported. The reduction rate is dependent on the concentration of substrate (Cr6+), oxidant (HCOOH), and catalyst, pH, temperature, and foreign ions. The PANI/MnO2/TiO2 reveals an excellent conversion (99.9%), rate constant (15.97 × 10–2 min–1), and turnover frequency (0.3333 mmol/mg/min) in the reduction of Cr6+. The results obtained from this study illustrate that the prepared nanocomposite, PANI/MnO2/TiO2, can be very well used as an effective and ..." @default.
• W2748921036 created "2017-08-31" @default.
• W2748921036 creator A5009465443 @default.
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• W2748921036 date "2017-08-25" @default.
• W2748921036 modified "2023-09-25" @default.
• W2748921036 title "Reduction of Cr⁶⁺ from Wastewater Using a Novel <i>in Situ</i>-Synthesized PANI/MnO₂/TiO₂ Nanocomposite: Renewable, Selective, Stable, and Synergistic Catalysis" @default.
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• W2748921036 doi "https://doi.org/10.1021/acssuschemeng.7b02324" @default.
• W2748921036 hasPublicationYear "2017" @default.
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