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- W2748934934 abstract "Primary and secondary straight-chain alcohols with one to eight carbon atoms have been analysed by gas chromatography at 100° on 3-m columns packed with 20% of squalane and Carbowax 400, 1000 and 20M, on chlorodimethylsilane-treated Chromosorb W (60–80 mesh), using thermal-conductivity and flame-ionization detectors. The specific retention volumes, Vg, and the retention indices relative to normal alcohols, have been determined for all of the compounds, and the effects of the positions of the hydroxyl groups have been investigated. Boiling points, vapour pressures and molecular volumes have been correlated with the measured retention values. The activity coefficients at infinite dilution and the normalized activity coefficients have been calculated, and their influence on the separation is discussed." @default.
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- W2748934934 date "1977-01-01" @default.
- W2748934934 modified "2023-09-26" @default.
- W2748934934 title "The correlation between the physical properties and structure of alcohols and their gas chromatographic behaviour on polar and non-polar stationary phases" @default.
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- W2748934934 doi "https://doi.org/10.1016/s0021-9673(00)80919-x" @default.
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