FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2749273705> ?p ?o ?g. }

• W2749273705 endingPage "25359" @default.
• W2749273705 startingPage "25352" @default.
• W2749273705 abstract "The solvation properties of protic ionic liquids such as alkylammonium salts are still virtually uncharacterized. Both electrostatic interactions between charged particles and hydrogen bond networks in a solvent are known to hinder the solubility of apolar species. Protic ionic liquids can be a priori expected to dissolve hydrocarbons worse than aprotic ionic liquids which do not form hydrogen bonds between the ions. We measured the limiting activity coefficients of several alkanes and alkylbenzenes in propylammonium and butylammonium nitrates at 298 K. Surprisingly, we observed the tendency of higher solubility than for the same compounds in aprotic ionic liquids with a similar molar volume. The calculations of the excess Gibbs free energies using test particle insertions into the snapshots of molecular dynamics trajectories reproduced lower values in protic rather than in aprotic ionic liquids for both methane molecules and hard sphere solutes. This can be explained by the favorable solvation of apolar species in the apolar domain of nanostructured PILs. For the first time, we point out at the essential difference between the solvation properties of two types of ionic liquids and prove that it arises from the cavity formation term." @default.
• W2749273705 created "2017-08-31" @default.
• W2749273705 creator A5009852444 @default.
• W2749273705 creator A5031263313 @default.
• W2749273705 creator A5043402593 @default.
• W2749273705 creator A5054580908 @default.
• W2749273705 date "2017-01-01" @default.
• W2749273705 modified "2023-10-07" @default.
• W2749273705 title "Solvation of apolar compounds in protic ionic liquids: the non-synergistic effect of electrostatic interactions and hydrogen bonds" @default.
• W2749273705 cites W1973446924 @default.
• W2749273705 cites W1982633565 @default.
• W2749273705 cites W1990178568 @default.
• W2749273705 cites W2006755239 @default.
• W2749273705 cites W2009755440 @default.
• W2749273705 cites W2015517515 @default.
• W2749273705 cites W2024135405 @default.
• W2749273705 cites W2033869281 @default.
• W2749273705 cites W2036943229 @default.
• W2749273705 cites W2050644222 @default.
• W2749273705 cites W2054934172 @default.
• W2749273705 cites W2055890467 @default.
• W2749273705 cites W2062633203 @default.
• W2749273705 cites W2081023938 @default.
• W2749273705 cites W2083018027 @default.
• W2749273705 cites W2085806783 @default.
• W2749273705 cites W2089439093 @default.
• W2749273705 cites W2093233380 @default.
• W2749273705 cites W2122005328 @default.
• W2749273705 cites W2131609458 @default.
• W2749273705 cites W2146538210 @default.
• W2749273705 cites W2237541751 @default.
• W2749273705 cites W2314630952 @default.
• W2749273705 cites W2315208792 @default.
• W2749273705 cites W2325961087 @default.
• W2749273705 cites W2332785528 @default.
• W2749273705 cites W2336515436 @default.
• W2749273705 cites W2364897399 @default.
• W2749273705 cites W2529276053 @default.
• W2749273705 cites W2952158242 @default.
• W2749273705 doi "https://doi.org/10.1039/c7cp05249a" @default.
• W2749273705 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28892108" @default.
• W2749273705 hasPublicationYear "2017" @default.
• W2749273705 type Work @default.
• W2749273705 sameAs 2749273705 @default.
• W2749273705 citedByCount "19" @default.
• W2749273705 countsByYear W27492737052018 @default.
• W2749273705 countsByYear W27492737052019 @default.
• W2749273705 countsByYear W27492737052020 @default.
• W2749273705 countsByYear W27492737052021 @default.
• W2749273705 countsByYear W27492737052022 @default.
• W2749273705 countsByYear W27492737052023 @default.
• W2749273705 crossrefType "journal-article" @default.
• W2749273705 hasAuthorship W2749273705A5009852444 @default.
• W2749273705 hasAuthorship W2749273705A5031263313 @default.
• W2749273705 hasAuthorship W2749273705A5043402593 @default.
• W2749273705 hasAuthorship W2749273705A5054580908 @default.
• W2749273705 hasBestOaLocation W27492737051 @default.
• W2749273705 hasConcept C112887158 @default.
• W2749273705 hasConcept C145148216 @default.
• W2749273705 hasConcept C147597530 @default.
• W2749273705 hasConcept C147789679 @default.
• W2749273705 hasConcept C148093993 @default.
• W2749273705 hasConcept C149823470 @default.
• W2749273705 hasConcept C154881586 @default.
• W2749273705 hasConcept C155574463 @default.
• W2749273705 hasConcept C159467904 @default.
• W2749273705 hasConcept C161790260 @default.
• W2749273705 hasConcept C178790620 @default.
• W2749273705 hasConcept C179104552 @default.
• W2749273705 hasConcept C185592680 @default.
• W2749273705 hasConcept C2182769 @default.
• W2749273705 hasConcept C2777691172 @default.
• W2749273705 hasConcept C2779348937 @default.
• W2749273705 hasConcept C2780471494 @default.
• W2749273705 hasConcept C32909587 @default.
• W2749273705 hasConceptScore W2749273705C112887158 @default.
• W2749273705 hasConceptScore W2749273705C145148216 @default.
• W2749273705 hasConceptScore W2749273705C147597530 @default.
• W2749273705 hasConceptScore W2749273705C147789679 @default.
• W2749273705 hasConceptScore W2749273705C148093993 @default.
• W2749273705 hasConceptScore W2749273705C149823470 @default.
• W2749273705 hasConceptScore W2749273705C154881586 @default.
• W2749273705 hasConceptScore W2749273705C155574463 @default.
• W2749273705 hasConceptScore W2749273705C159467904 @default.
• W2749273705 hasConceptScore W2749273705C161790260 @default.
• W2749273705 hasConceptScore W2749273705C178790620 @default.
• W2749273705 hasConceptScore W2749273705C179104552 @default.
• W2749273705 hasConceptScore W2749273705C185592680 @default.
• W2749273705 hasConceptScore W2749273705C2182769 @default.
• W2749273705 hasConceptScore W2749273705C2777691172 @default.
• W2749273705 hasConceptScore W2749273705C2779348937 @default.
• W2749273705 hasConceptScore W2749273705C2780471494 @default.
• W2749273705 hasConceptScore W2749273705C32909587 @default.
• W2749273705 hasIssue "37" @default.
• W2749273705 hasLocation W27492737051 @default.
• W2749273705 hasLocation W27492737052 @default.
• W2749273705 hasOpenAccess W2749273705 @default.
• W2749273705 hasPrimaryLocation W27492737051 @default.

• next