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- W2749499819 abstract "Abstract Unprotected tertiary sulfonimidamides have been prepared in good to excellent yields in a one‐pot transformation from tertiary sulfinamides through NH transfer. The reaction is mediated by commercially available (diacetoxyiodo)benzene and ammonium carbamate in methanol under convenient conditions. A wide range of functional groups are tolerated and initial results indicate that the NH transfer is stereospecific. A small molecule X‐ray analysis of NH sulfonimidamide 2 a and its behavior in selected in vitro assays in comparison to the matched sulfonamide are also reported. This new reaction provides a safe, short and efficient approach to sulfonimidamides, which have been the subject of recent, growing interest in the life sciences." @default.
- W2749499819 created "2017-08-31" @default.
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- W2749499819 date "2017-10-09" @default.
- W2749499819 modified "2023-10-18" @default.
- W2749499819 title "A New, Practical One-Pot Synthesis of Unprotected Sulfonimidamides by Transfer of Electrophilic NH to Sulfinamides" @default.
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- W2749499819 doi "https://doi.org/10.1002/chem.201703272" @default.
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