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• W2749536864 abstract "An especial current collector of Ti pillar arrays (Ti Ps) is prepared by a facile hydrothermal etching method. The Ti Ps substrate can be applied in acidic medium for its excellent stability, and the large specific surface area of this substrate is highly beneficial to the contact between electrolyte and catalyst. Pd deposited on the Ti Ps substrate is selected to be the catalyst for H2O2 reduction due to its remarkable electrocatalytic activity and stability. The structure and phase composition of the Pd modified Ti Ps ([email protected] Ps) electrode are studied through X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and inductive coupled plasma emission spectrometer (ICP). The electrocatalytic property of the [email protected] Ps electrode is studied through cyclic voltammetry (CV) and chronoamperometry (CA). According to the results, the [email protected] Ps electrode exhibits a high reduction current density of 220 mA cm−2 at −0.2 V in 2 mol L−1 H2SO4 and 0.5 mol L−1 H2O2 which is greatly larger than that on Pd modified Ti plate ([email protected] plate) electrode. The activation energy of H2O2 reduction on this electrode is 19.77 kJ mol−1. The low activation energy and high electrocatalytic activity indicate that the as-prepared electrode can be applied as a potential cathode for fuel cell." @default.
• W2749536864 created "2017-08-31" @default.
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• W2749536864 date "2017-10-01" @default.
• W2749536864 modified "2023-10-12" @default.
• W2749536864 title "Investigation of palladium nanoparticles supported on metallic titanium pillars as a novel electrode for hydrogen peroxide electroreduction in acidic medium" @default.
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• W2749536864 doi "https://doi.org/10.1016/j.electacta.2017.08.053" @default.
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