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- W2749799098 startingPage "e1700158" @default.
- W2749799098 abstract "The full details of mechanistic investigation on enantioselective sulfenofunctionalization of alkenes under Lewis base catalysis are described. Solution spectroscopic identification of the catalytically active sulfenylating agent has been accomplished along with the spectroscopic identification of putative thiiranium ion intermediates generated in the enantiodetermining step. The structural insights gleaned from these studies informed the design of new catalyst architectures to improve enantioselectivity. In addition, structural modification of the sulfenylating agents had a significant and salutary effect on the enantioselectivity of sulfenofunctionalization which was demonstrated to be general for trans disubstituted alkenes. Whereas electronic modulation had little effect on the rate and selectivity, steric bulk on arylsulfenylphthalimides was very beneficial." @default.
- W2749799098 created "2017-08-31" @default.
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- W2749799098 date "2017-09-01" @default.
- W2749799098 modified "2023-09-24" @default.
- W2749799098 title "Structural, Mechanistic, Spectroscopic, and Preparative Studies on the <i>Lewis</i> Base Catalyzed, Enantioselective Sulfenofunctionalization of Alkenes" @default.
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- W2749799098 doi "https://doi.org/10.1002/hlca.201700158" @default.
- W2749799098 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/5755611" @default.
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