FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2750016965> ?p ?o ?g. }

• W2750016965 abstract "We combined high-resolution Fourier-transform spectroscopy and large-scale electronic structure calculation to study energy and radiative properties of the high-lying (3)1{Pi} and (5)1{Sigma}+ states of the RbCs molecule. The laser-induced (5)1{Sigma}+(4)1{Sigma}+(3)1{Pi}-A(2)1{Sigma}+ b(1)3{Pi} fluorescence (LIF) spectra were recorded by the Bruker IFS-125(HR) spectrometer in the frequency range {nu} 5500 to 10000cm-1 with the instrumental resolution of 0.03 cm-1. The rotational assignment of the observed LIF progressions, which exhibit irregular vibrational-rotational spacing due to strong spin-orbit interaction between A1{Sigma}+ and b3(Pi) states was based on the coincidences between observed and calculated energy differences. The required rovibronic term values of the strongly perturbed A-b complex have been calculated by a coupled-channels approach for both 85Rb133Cs and 87Rb133Cs isotopologs with accuracy of about 0.01 cm-1, as demonstrated in A. Kruzins et al. [J. Chem. Phys. 141, 184309 (2014)]. The experimental energies of the upper (3)1(Pi) and (5)1{Sigma}+ states were involved in a direct-potential-fit analysis performed in the framework of inverted perturbation approach. Quasirelativistic ab initio calculations of the spin-allowed (3)1{Pi},(5)1{Sigma}+- (1-4)1{Sigma}+(1-3)1{Pi} transition dipole moments were performed. Radiative lifetimes and vibronic branching ratios of radiative transitions from the (3)1{Pi} and (5)1{Sigma}+ states were evaluated. To elucidate the origin of the {Lambda}-doubling effect in the (3)1{Pi} state, the angular coupling (3)1{Pi}-(1-5)1{Sigma}+ electronic matrix elements were calculated and applied for the relevant q-factors estimate. The intensity distributions simulated for the particular (5)1{Sigma}+(3)1{Pi}-A-b LIF progressions have been found to be remarkably close to their experimental counterparts." @default.
• W2750016965 created "2017-08-31" @default.
• W2750016965 creator A5005817118 @default.
• W2750016965 creator A5062788695 @default.
• W2750016965 creator A5066149235 @default.
• W2750016965 creator A5076954648 @default.
• W2750016965 creator A5079872803 @default.
• W2750016965 creator A5087341869 @default.
• W2750016965 creator A5022469337 @default.
• W2750016965 date "2017-08-11" @default.
• W2750016965 modified "2023-09-24" @default.
• W2750016965 title "Energy and radiative properties of the <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:mo>(</mml:mo><mml:mn>3</mml:mn><mml:mo>)</mml:mo><mml:mmultiscripts><mml:mi mathvariant=normal>Π</mml:mi><mml:mprescripts /><mml:none /><mml:mn>1</mml:mn></mml:mmultiscripts></mml:mrow></mml:math> and <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:mo>(</mml:mo><mml:mn>5</mml:mn><mml:mo>)</mml:mo><mml:mmultiscripts><mml:mi mathvariant=normal>Σ</mml:mi><mml:…" @default.
• W2750016965 cites W1555806863 @default.
• W2750016965 cites W1970756691 @default.
• W2750016965 cites W1971780118 @default.
• W2750016965 cites W1975620449 @default.
• W2750016965 cites W2013441715 @default.
• W2750016965 cites W2015725560 @default.
• W2750016965 cites W2017351510 @default.
• W2750016965 cites W2025049500 @default.
• W2750016965 cites W2037269166 @default.
• W2750016965 cites W2037609543 @default.
• W2750016965 cites W2038207191 @default.
• W2750016965 cites W2038922877 @default.
• W2750016965 cites W2049459958 @default.
• W2750016965 cites W2049656217 @default.
• W2750016965 cites W2053967659 @default.
• W2750016965 cites W2057041600 @default.
• W2750016965 cites W2058929032 @default.
• W2750016965 cites W2073508646 @default.
• W2750016965 cites W2076459268 @default.
• W2750016965 cites W2090194098 @default.
• W2750016965 cites W2091896053 @default.
• W2750016965 cites W2126797778 @default.
• W2750016965 cites W2157946589 @default.
• W2750016965 cites W2235828629 @default.
• W2750016965 cites W2313199012 @default.
• W2750016965 cites W2319943484 @default.
• W2750016965 cites W2469817556 @default.
• W2750016965 cites W3101342877 @default.
• W2750016965 cites W3105011466 @default.
• W2750016965 cites W3112994594 @default.
• W2750016965 cites W4242755817 @default.
• W2750016965 doi "https://doi.org/10.1103/physreva.96.022510" @default.
• W2750016965 hasPublicationYear "2017" @default.
• W2750016965 type Work @default.
• W2750016965 sameAs 2750016965 @default.
• W2750016965 citedByCount "5" @default.
• W2750016965 countsByYear W27500169652018 @default.
• W2750016965 countsByYear W27500169652019 @default.
• W2750016965 countsByYear W27500169652020 @default.
• W2750016965 countsByYear W27500169652021 @default.
• W2750016965 crossrefType "journal-article" @default.
• W2750016965 hasAuthorship W2750016965A5005817118 @default.
• W2750016965 hasAuthorship W2750016965A5022469337 @default.
• W2750016965 hasAuthorship W2750016965A5062788695 @default.
• W2750016965 hasAuthorship W2750016965A5066149235 @default.
• W2750016965 hasAuthorship W2750016965A5076954648 @default.
• W2750016965 hasAuthorship W2750016965A5079872803 @default.
• W2750016965 hasAuthorship W2750016965A5087341869 @default.
• W2750016965 hasBestOaLocation W27500169652 @default.
• W2750016965 hasConcept C121332964 @default.
• W2750016965 hasConcept C184779094 @default.
• W2750016965 hasConcept C186370098 @default.
• W2750016965 hasConcept C2778049214 @default.
• W2750016965 hasConcept C2781442258 @default.
• W2750016965 hasConcept C32891209 @default.
• W2750016965 hasConcept C4839761 @default.
• W2750016965 hasConcept C62520636 @default.
• W2750016965 hasConcept C74902906 @default.
• W2750016965 hasConceptScore W2750016965C121332964 @default.
• W2750016965 hasConceptScore W2750016965C184779094 @default.
• W2750016965 hasConceptScore W2750016965C186370098 @default.
• W2750016965 hasConceptScore W2750016965C2778049214 @default.
• W2750016965 hasConceptScore W2750016965C2781442258 @default.
• W2750016965 hasConceptScore W2750016965C32891209 @default.
• W2750016965 hasConceptScore W2750016965C4839761 @default.
• W2750016965 hasConceptScore W2750016965C62520636 @default.
• W2750016965 hasConceptScore W2750016965C74902906 @default.
• W2750016965 hasIssue "2" @default.
• W2750016965 hasLocation W27500169651 @default.
• W2750016965 hasLocation W27500169652 @default.
• W2750016965 hasOpenAccess W2750016965 @default.
• W2750016965 hasPrimaryLocation W27500169651 @default.
• W2750016965 hasRelatedWork W1608212971 @default.
• W2750016965 hasRelatedWork W1990119712 @default.
• W2750016965 hasRelatedWork W2024596432 @default.
• W2750016965 hasRelatedWork W2025120862 @default.
• W2750016965 hasRelatedWork W2028039437 @default.
• W2750016965 hasRelatedWork W2033612777 @default.
• W2750016965 hasRelatedWork W2034472000 @default.
• W2750016965 hasRelatedWork W2055696966 @default.
• W2750016965 hasRelatedWork W2095275006 @default.
• W2750016965 hasRelatedWork W2802730251 @default.
• W2750016965 hasVolume "96" @default.
• W2750016965 isParatext "false" @default.
• W2750016965 isRetracted "false" @default.
• W2750016965 magId "2750016965" @default.
• W2750016965 workType "article" @default.