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• W2750393826 endingPage "4558" @default.
• W2750393826 startingPage "4552" @default.
• W2750393826 abstract "Cocrystallization of [Me 3 NH] 2 [B 12 Y 12 ] (Y = Cl, Br, I) with 1 equiv. of [Me 3 NH]X (X = Cl, Br) from acetonitrile/diethyl ether solution produced large colorless single crystals of [(Me 3 NH) 3 X][B 12 Y 12 ]. Four different compounds of this type were prepared and structurally characterized. The compounds consist of weakly coordinating perhalogenated closo ‐dodecaborate [B 12 Y 12 ] 2– dianions and unprecedented weakly bound discrete [(Me 3 NH) 3 X] 2+ dications. The [(Me 3 NH) 3 X] 2+ dications are built up from a central halide anion and three [Me 3 NH] + cations bound by N–H ··· X hydrogen bonds. The cations have a pyramidal structure, as determined by X‐ray diffraction, which is in contrast to quantum‐chemical calculations, which predict a trigonal‐planar structure. While the [(Me 3 NH) 3 Cl] 2+ and [(Me 3 NH) 3 Br] 2+ cations were easily prepared, attempts to synthesize the corresponding [(Me 3 NH) 3 F] 2+ and [(Me 3 NH) 3 I] 2+ cations failed. Three further crystal structures containing the angulated [(Me 3 NH) 2 X] + cation stabilized by [B 12 Cl 12 ] 2– , [B 12 Br 12 ] 2– , or [Me 3 NB 12 Cl 11 ] – are reported as well." @default.
• W2750393826 created "2017-08-31" @default.
• W2750393826 creator A5008366565 @default.
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• W2750393826 creator A5070161482 @default.
• W2750393826 date "2017-08-21" @default.
• W2750393826 modified "2023-10-04" @default.
• W2750393826 title "Halogenated <i>closo</i> ‐Dodecaborate Anions Stabilize Weakly Bound [(Me ₃ NH) ₃ X] ²⁺ (X = Cl, Br) Dications in the Solid State" @default.
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• W2750393826 doi "https://doi.org/10.1002/ejic.201700620" @default.
• W2750393826 hasPublicationYear "2017" @default.
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