FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2750393945> ?p ?o ?g. }

• W2750393945 endingPage "1333" @default.
• W2750393945 startingPage "1326" @default.
• W2750393945 abstract "Abstract In order to better understand the haloacetic acid (HAA) photodegradation process, this study investigated the kinetics, mechanisms, and products of seven chlorinated (Cl-), brominated (Br-), and iodinated (I-) HAAs irradiated with 254 nm ultraviolet light (UV254). The photodegradation rates of HAAs by UV254 alone were found to increase with increasing halogenation degrees (i.e., tri > di > mono) and molecular weights (i.e., I > Br > Cl), and the kinetic trends from both literature and this study were well captured by a quantitative structure activity relationship model, which reveals that molar absorptivity of compound is the most important property of HAAs in defining its photo-susceptibility. Interestingly, although direct photolysis was dominant for all HAAs removal, indirect photolysis via generation of hydroxyl radicals due to photodecomposition of degradation intermediates such as formic acid also contributes partially (26–47%) to the losses of Cl-HAAs. Degradation products and pathways varied significantly among HAAs too. While Cl-HAAs mainly underwent mineralization with carbon dioxide being the major product, Br- and I-HAAs experienced stepwise dehalogenation and decarboxylation processes, which resulted in substantial halogen-free organic compounds. The common products of HAAs photolysis are halide(s), formic acid, formaldehyde, and halomethanes, symbolizing three concurrent pathways. Overall, the findings clearly demonstrated the dramatic differences between Cl- and Br-/I-HAAs, and indirectly evidenced the presence of hydroxyl radical during HAA irradiation even without addition of catalyst." @default.
• W2750393945 created "2017-08-31" @default.
• W2750393945 creator A5015997243 @default.
• W2750393945 creator A5016029335 @default.
• W2750393945 creator A5055723755 @default.
• W2750393945 creator A5073216396 @default.
• W2750393945 creator A5081713819 @default.
• W2750393945 date "2017-12-01" @default.
• W2750393945 modified "2023-09-30" @default.
• W2750393945 title "A comparison of photodegradation kinetics, mechanisms, and products between chlorinated and brominated/iodinated haloacetic acids in water" @default.
• W2750393945 cites W1698834950 @default.
• W2750393945 cites W1966456539 @default.
• W2750393945 cites W1966919482 @default.
• W2750393945 cites W1972756092 @default.
• W2750393945 cites W1974670990 @default.
• W2750393945 cites W1976068152 @default.
• W2750393945 cites W1977260209 @default.
• W2750393945 cites W1981206423 @default.
• W2750393945 cites W1989340265 @default.
• W2750393945 cites W1993147084 @default.
• W2750393945 cites W1998343061 @default.
• W2750393945 cites W1999037052 @default.
• W2750393945 cites W2004879472 @default.
• W2750393945 cites W2010307674 @default.
• W2750393945 cites W2012530988 @default.
• W2750393945 cites W2013029969 @default.
• W2750393945 cites W2017202116 @default.
• W2750393945 cites W2021211875 @default.
• W2750393945 cites W2021336108 @default.
• W2750393945 cites W2025362086 @default.
• W2750393945 cites W2033486440 @default.
• W2750393945 cites W2034997596 @default.
• W2750393945 cites W2035809268 @default.
• W2750393945 cites W2038172277 @default.
• W2750393945 cites W2042113356 @default.
• W2750393945 cites W2043127365 @default.
• W2750393945 cites W2044657168 @default.
• W2750393945 cites W2049063210 @default.
• W2750393945 cites W2053783788 @default.
• W2750393945 cites W2057402721 @default.
• W2750393945 cites W2060984328 @default.
• W2750393945 cites W2062658304 @default.
• W2750393945 cites W2063283197 @default.
• W2750393945 cites W2072396093 @default.
• W2750393945 cites W2078401896 @default.
• W2750393945 cites W2079666988 @default.
• W2750393945 cites W2085737048 @default.
• W2750393945 cites W2085761533 @default.
• W2750393945 cites W2088361943 @default.
• W2750393945 cites W2157158086 @default.
• W2750393945 cites W2168578603 @default.
• W2750393945 cites W2171530751 @default.
• W2750393945 cites W2232192360 @default.
• W2750393945 cites W2288703130 @default.
• W2750393945 cites W2318305681 @default.
• W2750393945 cites W2323389591 @default.
• W2750393945 cites W2323601547 @default.
• W2750393945 cites W2325777070 @default.
• W2750393945 cites W2336456844 @default.
• W2750393945 cites W2396327396 @default.
• W2750393945 cites W2413629854 @default.
• W2750393945 cites W2461217359 @default.
• W2750393945 cites W2510875266 @default.
• W2750393945 cites W2516587586 @default.
• W2750393945 cites W2519681033 @default.
• W2750393945 cites W2529957433 @default.
• W2750393945 cites W2559440162 @default.
• W2750393945 cites W2570574853 @default.
• W2750393945 cites W2588923090 @default.
• W2750393945 cites W943770219 @default.
• W2750393945 doi "https://doi.org/10.1016/j.cej.2017.08.086" @default.
• W2750393945 hasPublicationYear "2017" @default.
• W2750393945 type Work @default.
• W2750393945 sameAs 2750393945 @default.
• W2750393945 citedByCount "39" @default.
• W2750393945 countsByYear W27503939452018 @default.
• W2750393945 countsByYear W27503939452019 @default.
• W2750393945 countsByYear W27503939452020 @default.
• W2750393945 countsByYear W27503939452021 @default.
• W2750393945 countsByYear W27503939452022 @default.
• W2750393945 countsByYear W27503939452023 @default.
• W2750393945 crossrefType "journal-article" @default.
• W2750393945 hasAuthorship W2750393945A5015997243 @default.
• W2750393945 hasAuthorship W2750393945A5016029335 @default.
• W2750393945 hasAuthorship W2750393945A5055723755 @default.
• W2750393945 hasAuthorship W2750393945A5073216396 @default.
• W2750393945 hasAuthorship W2750393945A5081713819 @default.
• W2750393945 hasConcept C107872376 @default.
• W2750393945 hasConcept C121332964 @default.
• W2750393945 hasConcept C148898269 @default.
• W2750393945 hasConcept C161790260 @default.
• W2750393945 hasConcept C162847780 @default.
• W2750393945 hasConcept C178790620 @default.
• W2750393945 hasConcept C185592680 @default.
• W2750393945 hasConcept C2777637177 @default.
• W2750393945 hasConcept C2779679103 @default.
• W2750393945 hasConcept C41008148 @default.
• W2750393945 hasConcept C505241676 @default.

• next