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- W2750813682 abstract "Abstract The crystallization of terbium 5,5′‐azobis[1H‐tetrazol‐1‐ide] (ZT) in the presence of trace amounts (ca. 50 Bq, ca. 1.6 pmol) of americium results in 1) the accumulation of the americium tracer in the crystalline solid and 2) a material that adopts a different crystal structure to that formed in the absence of americium. Americium‐doped [Tb(Am)(H 2 O) 7 ZT] 2 ZT⋅10 H 2 O is isostructural to light lanthanide (Ce–Gd) 5,5′‐azobis[1H‐tetrazol‐1‐ide] compounds, rather than to the heavy lanthanide (Tb–Lu) 5,5′‐azobis[1 H ‐tetrazol‐1‐ide] (e.g., [Tb(H 2 O) 8 ] 2 ZT 3 ⋅6 H 2 O) derivatives. Traces of Am seem to force the Tb compound into a structure normally preferred by the lighter lanthanides, despite a 10 8 ‐fold Tb excess. The americium‐doped material was studied by single‐crystal X‐ray diffraction, vibrational spectroscopy, radiochemical neutron activation analysis, and scanning electron microcopy. In addition, the inclusion properties of terbium 5,5′‐azobis[1H‐tetrazol‐1‐ide] towards americium were quantified, and a model for the crystallization process is proposed." @default.
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- W2750813682 date "2017-08-31" @default.
- W2750813682 modified "2023-10-14" @default.
- W2750813682 title "Picomolar Traces of Americium(III) Introduce Drastic Changes in the Structural Chemistry of Terbium(III): A Break in the “Gadolinium Break”" @default.
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- W2750813682 doi "https://doi.org/10.1002/anie.201703971" @default.
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