FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2750876398> ?p ?o ?g. }

• W2750876398 abstract "Only a bold man would dare attempt a synthesis of the wide-ranging discussions of the last two days, let alone distil from them any general principles of biological recognition. The only sentiment which could command general assent is one of gratitude to the Society, the organizers and the contributors for putting before us such a fascinating collection of papers and letting us sharpen our wits on so much new knowledge. The following remarks will therefore be nothing more than personal footnotes; if they omit reference to much of the work which has been presented, and only mention a few of the issues that have been raised, that is a matter of sheer necessity, not of personal prejudice. In our first session we began by reviewing the physical chemistry of molecular interactions in terms of quantum mechanics and statistical mechanics. Professor Buckingham warned us against the temptation of regarding molecular association energies as made up of additive contributions from pairs of atoms or ions, and Professor Symons stressed the highly individual structure-forming habits of water, which make it so difficult to interpret its solvation properties in terms of simplified models which treat water as a uniform dielectric, or as a mixture of monomers and high polymers. Professor Truter then introduced us to the structures of the complexes formed by ferrichrome A, nonactin and other biological agents with metal ions of various kinds. She drew attention to the large conformational changes which often accompany complex formation, and suggested that some at least of these agents owe their specificity to their high flexibility. Presumably one should interpret this generalization in terms of an ability of the complexing agent to meet very precisely the stereochemical needs of one particular ion, coupled with an inability to meet the precise needs of other ions without a certain amount of mechanical strain. To take a single example, it is not immediately obvious how the needs of T1+ differ from those of the alkali metal ions; but that is because we tend to overlook the effect of ionic polarization on the stability of the solvated ion. The T1 + ion, because of its outer electron pair, has a low-lying dipole transition (6s -> 6p) which confers on it a high electric polarizability. As a result, a set of negative ligands on one side induce a negative charge on the other side, and this will hinder the approach of further ligands on that side - as suggested by the curious stereochemistry of some of Professor Truter’s T1 + complexes." @default.
• W2750876398 created "2017-09-15" @default.
• W2750876398 creator A5066121812 @default.
• W2750876398 date "1975-11-06" @default.
• W2750876398 modified "2023-10-18" @default.
• W2750876398 title "Closing remarks" @default.
• W2750876398 cites W2002931001 @default.
• W2750876398 doi "https://doi.org/10.1098/rstb.1975.0082" @default.
• W2750876398 hasPublicationYear "1975" @default.
• W2750876398 type Work @default.
• W2750876398 sameAs 2750876398 @default.
• W2750876398 citedByCount "0" @default.
• W2750876398 crossrefType "journal-article" @default.
• W2750876398 hasAuthorship W2750876398A5066121812 @default.
• W2750876398 hasConcept C111472728 @default.
• W2750876398 hasConcept C121332964 @default.
• W2750876398 hasConcept C136815107 @default.
• W2750876398 hasConcept C138885662 @default.
• W2750876398 hasConcept C15744967 @default.
• W2750876398 hasConcept C185592680 @default.
• W2750876398 hasConcept C2779271205 @default.
• W2750876398 hasConcept C33332235 @default.
• W2750876398 hasConcept C77805123 @default.
• W2750876398 hasConceptScore W2750876398C111472728 @default.
• W2750876398 hasConceptScore W2750876398C121332964 @default.
• W2750876398 hasConceptScore W2750876398C136815107 @default.
• W2750876398 hasConceptScore W2750876398C138885662 @default.
• W2750876398 hasConceptScore W2750876398C15744967 @default.
• W2750876398 hasConceptScore W2750876398C185592680 @default.
• W2750876398 hasConceptScore W2750876398C2779271205 @default.
• W2750876398 hasConceptScore W2750876398C33332235 @default.
• W2750876398 hasConceptScore W2750876398C77805123 @default.
• W2750876398 hasLocation W27508763981 @default.
• W2750876398 hasOpenAccess W2750876398 @default.
• W2750876398 hasPrimaryLocation W27508763981 @default.
• W2750876398 hasRelatedWork W155667366 @default.
• W2750876398 hasRelatedWork W194391364 @default.
• W2750876398 hasRelatedWork W2025420477 @default.
• W2750876398 hasRelatedWork W2028044355 @default.
• W2750876398 hasRelatedWork W2037834351 @default.
• W2750876398 hasRelatedWork W2073321081 @default.
• W2750876398 hasRelatedWork W2157502295 @default.
• W2750876398 hasRelatedWork W2170868445 @default.
• W2750876398 hasRelatedWork W2181508240 @default.
• W2750876398 hasRelatedWork W2202364738 @default.
• W2750876398 hasRelatedWork W2294309290 @default.
• W2750876398 hasRelatedWork W2306954477 @default.
• W2750876398 hasRelatedWork W2319289418 @default.
• W2750876398 hasRelatedWork W2322174926 @default.
• W2750876398 hasRelatedWork W2337012593 @default.
• W2750876398 hasRelatedWork W263641931 @default.
• W2750876398 hasRelatedWork W2767447283 @default.
• W2750876398 hasRelatedWork W37674738 @default.
• W2750876398 hasRelatedWork W94711987 @default.
• W2750876398 hasRelatedWork W2471639547 @default.
• W2750876398 isParatext "false" @default.
• W2750876398 isRetracted "false" @default.
• W2750876398 magId "2750876398" @default.
• W2750876398 workType "article" @default.