Matches in SemOpenAlex for { <https://semopenalex.org/work/W2751054483> ?p ?o ?g. }
- W2751054483 abstract "A series of N,O-ketimine supported gallium and digallane complexes have been synthesized and structurally characterized. The mono(ketiminate) gallium dichloride [OCMeCHCMeN(Dipp)]GaCl2, 2 (Dipp=2,6-(Pr2C6H3)-Pr-i) and bis(ketiminate) gallium chloride [OCMeCHCMeN(Dipp)](2)GaCl, 3 were isolated from the reaction of GaCl3 with 1 and 2 equivalents of lithiated ketimine, [OCMeCHCMeN(Dipp)]Li, 1 respectively. Treatment of 1 with GaI'' yielded diiodobis(ketiminate) digallane complex [OCMeCHCMeN-(Dipp)](2)Ga2I2, 4. To the best of our knowledge, compound 4 is the first report on N,O-ketiminate ligand supported stable heteroleptic digallane(II) complex. The frontier molecular orbital analysis and a high Wiberg Bond Index (WBI) values support the strong interaction between the gallium centers in 4. In an attempt to synthesize alkyl substituted Ga complexes, we carried out the reaction of ketimine ligand with (GaBu2Cl)-Bu-t (1:1 ratio) that generated the adduct [OCMeCHCMeN(H)(Dipp)](GaBu2Cl)-Bu-t, 5. In a similar fashion, dialkyl gallium complex [OCMeCHCMeN(Dipp)](GaBu2)-Bu-t, 6 was obtained from the reaction of 1 with (GaBu2Cl)-Bu-t. All the compounds have been charecterized by H-1, (CNMR)-C-13 and mass spectroscopy. The molecular structures of complexes 2-5 have also been determined by single crystal X-ray diffraction analysis." @default.
- W2751054483 created "2017-09-15" @default.
- W2751054483 creator A5004684676 @default.
- W2751054483 creator A5018256857 @default.
- W2751054483 creator A5036801121 @default.
- W2751054483 creator A5049143428 @default.
- W2751054483 creator A5055786275 @default.
- W2751054483 creator A5075230954 @default.
- W2751054483 creator A5078948160 @default.
- W2751054483 date "2017-08-22" @default.
- W2751054483 modified "2023-10-18" @default.
- W2751054483 title "Synthesis, Structure and Chemistry of Mono- and Digallane Complexes Supported by N,O -Ketimine Ligand" @default.
- W2751054483 cites W1908171837 @default.
- W2751054483 cites W1966690187 @default.
- W2751054483 cites W1971778002 @default.
- W2751054483 cites W1982567581 @default.
- W2751054483 cites W1988099159 @default.
- W2751054483 cites W1989129353 @default.
- W2751054483 cites W1994567008 @default.
- W2751054483 cites W1995846984 @default.
- W2751054483 cites W1996213844 @default.
- W2751054483 cites W2001261332 @default.
- W2751054483 cites W2003182184 @default.
- W2751054483 cites W2008676135 @default.
- W2751054483 cites W2022297395 @default.
- W2751054483 cites W2025855655 @default.
- W2751054483 cites W2031354939 @default.
- W2751054483 cites W2032366589 @default.
- W2751054483 cites W2040384604 @default.
- W2751054483 cites W2040937605 @default.
- W2751054483 cites W2042061343 @default.
- W2751054483 cites W2055206190 @default.
- W2751054483 cites W2058604828 @default.
- W2751054483 cites W2060013781 @default.
- W2751054483 cites W2088297251 @default.
- W2751054483 cites W2099305121 @default.
- W2751054483 cites W2126928702 @default.
- W2751054483 cites W2134621184 @default.
- W2751054483 cites W2195886442 @default.
- W2751054483 cites W2287786686 @default.
- W2751054483 cites W2321894131 @default.
- W2751054483 cites W2332950207 @default.
- W2751054483 cites W2334096274 @default.
- W2751054483 cites W2474901067 @default.
- W2751054483 cites W2579906744 @default.
- W2751054483 cites W2582824092 @default.
- W2751054483 cites W2951127711 @default.
- W2751054483 cites W2953005871 @default.
- W2751054483 cites W4235456872 @default.
- W2751054483 cites W4238070159 @default.
- W2751054483 cites W4238334128 @default.
- W2751054483 cites W4241986113 @default.
- W2751054483 cites W4243023626 @default.
- W2751054483 cites W4243543508 @default.
- W2751054483 cites W4245103482 @default.
- W2751054483 cites W4254740003 @default.
- W2751054483 cites W4255756509 @default.
- W2751054483 doi "https://doi.org/10.1002/slct.201701634" @default.
- W2751054483 hasPublicationYear "2017" @default.
- W2751054483 type Work @default.
- W2751054483 sameAs 2751054483 @default.
- W2751054483 citedByCount "1" @default.
- W2751054483 countsByYear W27510544832018 @default.
- W2751054483 crossrefType "journal-article" @default.
- W2751054483 hasAuthorship W2751054483A5004684676 @default.
- W2751054483 hasAuthorship W2751054483A5018256857 @default.
- W2751054483 hasAuthorship W2751054483A5036801121 @default.
- W2751054483 hasAuthorship W2751054483A5049143428 @default.
- W2751054483 hasAuthorship W2751054483A5055786275 @default.
- W2751054483 hasAuthorship W2751054483A5075230954 @default.
- W2751054483 hasAuthorship W2751054483A5078948160 @default.
- W2751054483 hasConcept C116569031 @default.
- W2751054483 hasConcept C170493617 @default.
- W2751054483 hasConcept C185592680 @default.
- W2751054483 hasConcept C21951064 @default.
- W2751054483 hasConcept C55493867 @default.
- W2751054483 hasConcept C71240020 @default.
- W2751054483 hasConceptScore W2751054483C116569031 @default.
- W2751054483 hasConceptScore W2751054483C170493617 @default.
- W2751054483 hasConceptScore W2751054483C185592680 @default.
- W2751054483 hasConceptScore W2751054483C21951064 @default.
- W2751054483 hasConceptScore W2751054483C55493867 @default.
- W2751054483 hasConceptScore W2751054483C71240020 @default.
- W2751054483 hasFunder F4320334771 @default.
- W2751054483 hasLocation W27510544831 @default.
- W2751054483 hasLocation W27510544832 @default.
- W2751054483 hasOpenAccess W2751054483 @default.
- W2751054483 hasPrimaryLocation W27510544831 @default.
- W2751054483 hasRelatedWork W1814206567 @default.
- W2751054483 hasRelatedWork W1980377213 @default.
- W2751054483 hasRelatedWork W2044634666 @default.
- W2751054483 hasRelatedWork W2072777769 @default.
- W2751054483 hasRelatedWork W2077472737 @default.
- W2751054483 hasRelatedWork W2330215216 @default.
- W2751054483 hasRelatedWork W2739417245 @default.
- W2751054483 hasRelatedWork W2949431091 @default.
- W2751054483 hasRelatedWork W2952244581 @default.
- W2751054483 hasRelatedWork W2952276966 @default.
- W2751054483 isParatext "false" @default.
- W2751054483 isRetracted "false" @default.