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- W2751367060 abstract "The adsorption and photochemistry of CO on rutile TiO2(110) are studied with scanning tunneling microscopy (STM), temperature-programmed desorption, and angle-resolved photon-stimulated desorption (PSD) at low temperatures. Site occupancies, when weighted by the concentration of each kind of adsorption site on the reduced surface, show that the adsorption probability is the highest for the bridging oxygen vacancies (VO). The probability distribution for the different adsorption sites corresponds to very small differences in CO adsorption energies (<0.02 eV). UV irradiation stimulates diffusion and desorption of CO at low temperature. CO photodesorbs primarily from the vacancies with a bimodal angular distribution, indicating some scattering from the surface, which also leads to photostimulated diffusion. Hydroxylation of VO's does not significantly change the CO PSD yield or the angular distribution, which suggests that photodesorption can be initiated by recombination of photogenerated holes with excess electrons localized near the charged point defect (either VO or bridging hydroxyl)." @default.
- W2751367060 created "2017-09-15" @default.
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- W2751367060 date "2017-09-12" @default.
- W2751367060 modified "2023-10-03" @default.
- W2751367060 title "Adsorption and Photodesorption of CO from Charged Point Defects on TiO<sub>2</sub>(110)" @default.
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- W2751367060 doi "https://doi.org/10.1021/acs.jpclett.7b02052" @default.
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