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- W2751482934 abstract "A general and efficient way for enlarging the absorption wavelength of optical materials with high molar absorptivity was explored by incorporating a hydroxyl group ortho-position to a bridging group between the electron-withdrawing and the electron-donating groups. Both theoretical deduction and experimental data indicated that the molecular design strategy was rational and efficacious. Comparing to its analogy, the target materials, 3-hydroxyl-4-(N- ethyl-N-ethoxyl phenylazo) naphthalene sulfonic acid (HPNSA), possessed the improved optical property by extending the intrinsic D-π-A conjugated structure and selective recognition to Fe2+ by forming stable 5-member rings. Importantly, the proposed material was effectively applied for colorimetric determination of Fe2+ in four real environmental water samples with an accurate deviation of 4.0% and a low detection limit of 38 nmol L−1. The action mechanism between HPNSA and Fe2+ was investigated in detail." @default.
- W2751482934 created "2017-09-15" @default.
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- W2751482934 date "2017-11-01" @default.
- W2751482934 modified "2023-10-16" @default.
- W2751482934 title "Identification of a rigid and planar D-π-A conjugated system for colorimetric Fe(II) determination and its action mechanism" @default.
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- W2751482934 doi "https://doi.org/10.1016/j.optmat.2017.08.048" @default.
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