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- W2751619348 abstract "Tris(trimethylsilyl) phosphite (TMSP) has received considerable attention as a functional additive for various cathode materials in lithium-ion batteries, but the effect of TMSP on the surface stability of a graphite anode has not been studied. Herein, we demonstrate that TMSP serves as an effective solid electrolyte interphase (SEI)-forming additive for graphite anodes in lithium-ion batteries (LIBs). TMSP forms SEI layers by chemical reactions between TMSP and a reductively decomposed ethylene carbonate (EC) anion, which is strikingly different from the widely known mechanism of the SEI-forming additives. TMSP is stable under cathodic polarization, but it reacts chemically with radical anion intermediates derived from the electrochemical reduction of the carbonate solvents to generate a stable SEI layer. These TMSP-derived SEI layers improve the interfacial stability of the graphite anode, resulting in a retention of 96.8% and a high Coulombic efficiency of 95.2%. We suggest the use of TMSP as a functional additive that effectively stabilizes solid electrolyte interfaces of both the anode and cathode in lithium-ion batteries." @default.
- W2751619348 created "2017-09-15" @default.
- W2751619348 creator A5075494476 @default.
- W2751619348 creator A5077558935 @default.
- W2751619348 date "2017-09-18" @default.
- W2751619348 modified "2023-10-16" @default.
- W2751619348 title "Tris(trimethylsilyl) Phosphite as an Efficient Electrolyte Additive To Improve the Surface Stability of Graphite Anodes" @default.
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- W2751619348 doi "https://doi.org/10.1021/acsami.7b11309" @default.
- W2751619348 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28880070" @default.
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