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• W2751708082 abstract "A new, direct, and diastereoselective synthesis of activated 2,3,4,6-tetrasubstituted tetrahydro-2H-pyrans is described. In this reaction, iron(III) catalyzed an SN2'-Prins cyclization tandem process leading to the creation of three new stereocenters in one single step. These activated tetrahydro-2H-pyran units are easily derivatizable through CuAAC conjugations in order to generate multifunctionalized complex molecules. DFT calculations support the in situ SN2' reaction as a preliminary step in the Prins cyclization." @default.
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• W2751708082 date "2017-08-31" @default.
• W2751708082 modified "2023-10-18" @default.
• W2751708082 title "Direct Access to 2,3,4,6-Tetrasubstituted Tetrahydro-2<i>H</i>-pyrans via Tandem S_N2′–Prins Cyclization" @default.
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• W2751708082 doi "https://doi.org/10.1021/acs.orglett.7b02270" @default.
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