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- W2752508727 abstract "Abstract Well-crystallized NaYb(MoO 4 ) 2 doped with lanthanide ions (Ln 3+ : Er 3+ , Tm 3+ and Ho 3+ ) are successfully synthesized by hydrothermal method with further calcination. And the samples with different morphologies are obtained by changing the pH values and the molar ratio of Ln(NO 3 ) 3 /Na 2 MoO 4 of the resultant solutions. The upconversion (UC) luminescence spectra of NaYb(MoO 4 ) 2 : Ln 3+ between 323 K and 573 K under 980 nm excitation exhibit temperature-dependent property. The fluorescence intensity ratio (FIR) techniques with thermally coupled states (TCS) (Er 3+ : 2 H 11/2 , 4 S 3/2 → 4 I 15/2 , Tm 3+ : 1 G 4(1),(2) → 3 H 6 , Ho 3+ : 5 F 5(1),(2) → 5 I 8 ) have high sensitivity (S) values (Er 3+ : 0.0122 K −1 at 548 K, Tm 3+ : 0.0025 K −1 at 323 K and Ho 3+ : 0.00035 K −1 at 323 K). The non-TCS (Ho 3+ : 5 F 5 , 5 S 2 / 5 F 4 → 5 I 8 ) is used to extend the range of S, and the slope of FIR (non-TCS)-T is the S value as high as 0.02455 K -1 in the wide temperature range from 323 K to 573 K." @default.
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- W2752508727 date "2017-12-01" @default.
- W2752508727 modified "2023-10-14" @default.
- W2752508727 title "Ln3+ (Er3+, Tm3+ and Ho3+)-doped NaYb(MoO4)2 upconversion phosphors as wide range temperature sensors with high sensitivity" @default.
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- W2752508727 doi "https://doi.org/10.1016/j.jallcom.2017.09.010" @default.
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