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• W2753203526 endingPage "87" @default.
• W2753203526 startingPage "78" @default.
• W2753203526 abstract "Abstract In this work, simple solid state method was employed to synthesize Na2/3Ni1/3Mn2/3O2 which has two redox active transition metals. The electrochemical performance of the material was studied in a three electrode system with 1 M KOH aqueous solution as electrolyte, Hg/HgO as reference electrode and platinum wire as the counter electrode. Na2/3Ni1/5Mn4/5O2 and Na2/3MnO2 were also synthesized and used as control experiments to study the contribution of Ni in the complex. Our results confirmed that doping the base material (Na2/3MnO2) with an active mass of Ni increases the supercapacitive properties of the resulting material as a result of the multiple redox active sites offered by the two transition elements (Ni and Mn). Thus, the Na2/3Ni1/3Mn2/3O2 sample showed a specific capacitance of 532.121 F/g at a current density of 0.5 A/g while Na2/3Ni1/5Mn4/5O2 and Na2/3MnO2 samples showed specific capacitance of 283.50 F/g and 210.29 F/g respectively at a current density 0.5 A/g. Na2/3Ni1/3Mn2/3O2 also retained about 79% of its initial capacitance after 3000 cycles at 1.3 A/g." @default.
• W2753203526 created "2017-09-15" @default.
• W2753203526 creator A5051986226 @default.
• W2753203526 creator A5060613118 @default.
• W2753203526 date "2017-12-01" @default.
• W2753203526 modified "2023-09-29" @default.
• W2753203526 title "Layered Na2/3Ni1/3Mn2/3O2 as electrode material with two redox active transition metals for high performance supercapacitor" @default.
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• W2753203526 doi "https://doi.org/10.1016/j.jallcom.2017.08.276" @default.
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