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- W2753266685 abstract "The first enantioselective synthesis of (3S,4aR,8aR)-1 (the enantiomer of natural okundoperoxide) has been accomplished. The synthesis features: 1) stereoselective installation of the peroxy functionality (16 → 17); 2) ring opening of peroxyacetal and subsequent intramolecular reaction between the hydroperoxide and the vinyl epoxide to form the peroxy six-membered ring (5 → 1). The absolute configuration of okundoperoxide was determined to be 3R,4aS,8aS by comparing specific rotations of the synthetic sample and the natural product." @default.
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- W2753266685 date "2017-10-01" @default.
- W2753266685 modified "2023-10-18" @default.
- W2753266685 title "Synthesis of (−)-okundoperoxide and determination of the absolute configuration of natural (+)-okundoperoxide" @default.
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- W2753266685 doi "https://doi.org/10.1016/j.tetlet.2017.08.064" @default.
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