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- W2753454100 endingPage "5185" @default.
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- W2753454100 abstract "The tetramisole-promoted catalytic enantioselective [2,3]-sigmatropic rearrangement of quaternary ammonium salts bearing a (Z)-3-fluoro-3-arylprop-2-ene group generates, after addition of benzylamine, a range of β-fluoro-β-aryl-α-aminopentenamides containing a stereogenic tertiary fluorine substituent. Cyclic and acyclic nitrogen substituents as well as various aromatic substituents are tolerated, giving the β-fluoro-β-aryl-α-aminopentenamide products in up to 76% yield, 96:4 dr, and 98:2 er." @default.
- W2753454100 created "2017-09-15" @default.
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- W2753454100 date "2017-09-08" @default.
- W2753454100 modified "2023-09-27" @default.
- W2753454100 title "Enantioselective Synthesis of β-Fluoro-β-aryl-α-aminopentenamides by Organocatalytic [2,3]-Sigmatropic Rearrangement" @default.
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- W2753454100 doi "https://doi.org/10.1021/acs.orglett.7b02452" @default.
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