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- W2753649632 abstract "A procedure for the synthesis of well-defined random copolymers bearing multiple thiolate functionalities is presented. Reactive copolymers of vinylbenzyl chloride (VBC, 15 mol%) with methyl methacrylate (MMA, 85 mol%) were synthesized via free radical and RAFT polymerizations. The microstructure of these copolymers was characterized by monitoring the polymerization reaction. Post-polymerization modification of this reactive precursor was conducted by an initial substitution of VBC chloride with thiouronium (TU) followed by conversion of TU into thiolate via reaction with either KOH or NaBH4. The reaction with NaBH4, which was found to yield better result, was further investigated by monitoring the changes of the copolymer functional groups throughout the entire process using NMR. Further mechanistic insight was obtained by studying a model reaction between benzyl thiouronium, which is the small-molecule counterpart of TU-bearing vinylbenzyl repeating units, and NaBH4. Analysis of this model reaction confirmed the formation of thiolate groups and their subsequent transformation into inter or intra-molecular disulfide bonds." @default.
- W2753649632 created "2017-09-15" @default.
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- W2753649632 date "2017-10-01" @default.
- W2753649632 modified "2023-09-27" @default.
- W2753649632 title "RAFT polymerization, characterization, and post-polymerization modification of a copolymer of vinylbenzyl chloride: Towards thiolate functionalized copolymers" @default.
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- W2753649632 doi "https://doi.org/10.1016/j.polymer.2017.08.067" @default.
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