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• W2753794289 endingPage "10160" @default.
• W2753794289 startingPage "10153" @default.
• W2753794289 abstract "The external surfaces of metal-organic framework (MOF) materials are difficult to experimentally isolate due to the high porosities of these materials. MOF surface surrogates in the form of copper benzenedicarboxylate (CuBDC) nanosheets were synthesized using a bottom-up approach, and the surface interactions of water and ethanol were investigated by temperature-programmed desorption (TPD). A method of analysis of diffusion-influenced TPD was developed to measure the desorption properties of these porous materials. This approach also allows the extraction of diffusion coefficients from TPD data. The transmission Fourier transform infrared spectra, powder X-ray diffraction patterns, and TPD data indicate that water desorbs from CuBDC nanosheets with activation energies of 44 ± 2 kJ/mol at edge sites and 58 ± 1 kJ/mol at external surface and internal and pore sites. Ethanol desorbs with activation energies of 58 ± 1 kJ/mol at internal pore sites and 66 ± 0.4 kJ/mol at external surface sites. Co-adsorption of water and ethanol was also investigated. The presence of ethanol was found to inhibit the desorption of water, resulting in a water desorption process with an activation energy of 68 ± 0.7 kJ/mol." @default.
• W2753794289 created "2017-09-15" @default.
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• W2753794289 date "2017-09-21" @default.
• W2753794289 modified "2023-10-01" @default.
• W2753794289 title "Interactions on External MOF Surfaces: Desorption of Water and Ethanol from CuBDC Nanosheets" @default.
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• W2753794289 doi "https://doi.org/10.1021/acs.langmuir.7b01987" @default.
• W2753794289 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28877442" @default.
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