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• W2753892529 abstract "The N-heterocyclic-carbene-ligated ruthenium complex [RuHCl(CO)(H2IMes)(PCy3)] exhibits high catalytic activity for the (Z)-selective hydrosilylation of various terminal alkynes with 1,1,1,3,5,5,5-heptamethyltrisiloxane (HSiMe(OSiMe3)2). The stereoretentive derivatization of the (Z)-alkenylsiloxanes allows the synthesis of biologically active compounds, e.g. potent antitumor agents and inhibitors for induced-NO synthase." @default.
• W2753892529 created "2017-09-15" @default.
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• W2753892529 date "2017-09-08" @default.
• W2753892529 modified "2023-10-11" @default.
• W2753892529 title "(<i>Z</i>)-Selective Hydrosilylation of Terminal Alkynes with HSiMe(OSiMe₃)₂ Catalyzed by a Ruthenium Complex Containing an N-Heterocyclic Carbene" @default.
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• W2753892529 doi "https://doi.org/10.1021/acs.orglett.7b02477" @default.
• W2753892529 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28885855" @default.
• W2753892529 hasPublicationYear "2017" @default.
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