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• W2753992040 abstract "To address the growing demand for energy density, the Ni-rich layered [Ni0.90Co0.05Mn0.05]O2 cathode has been synthesized and its electrochemical performance in lithium-ion cells has been benchmarked against a lower-Ni content Li[Ni0.6Co0.2Mn0.2]O2 cathode. Li[Ni0.90Co0.05Mn0.05]O2 delivers a high discharge capacity of 227 mA h g–1 compared to a capacity of 189 mA h g–1 for Li[Ni0.6Co0.2Mn0.2]O2 when cycled up to a lower cutoff voltage of 4.3 V, making it an appealing candidate for electric vehicles. With an increase in the charge cutoff voltage to 4.5 V, Li[Ni0.90Co0.05Mn0.05]O2 displays a capacity of 238 mA h g–1 compared to a capacity of 208 mA h g–1 for Li[Ni0.6Co0.2Mn0.2]O2. Although Li[Ni0.90Co0.05Mn0.05]O2 suffers during cycling from the usual rapid capacity fade in a manner similar to that of LiNiO2, 87 and 81% of the initial capacity could still be retained after 100 cycles even after cycling to higher cutoff voltages of 4.3 and 4.5 V, respectively. A comparison of Li[Ni0.90Co0.05Mn0.05]O2 and Li..." @default.
• W2753992040 created "2017-09-25" @default.
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• W2753992040 date "2017-09-27" @default.
• W2753992040 modified "2023-10-17" @default.
• W2753992040 title "Impact of Microcrack Generation and Surface Degradation on a Nickel-Rich Layered Li[Ni_0.9Co_0.05Mn_0.05]O₂ Cathode for Lithium-Ion Batteries" @default.
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• W2753992040 doi "https://doi.org/10.1021/acs.chemmater.7b03268" @default.
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