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• W2754040742 abstract "The bis(NHC)borate-supported thorium-bis(mesitylphosphido) complex (1) undergoes reversible intramolecular C–H bond activation enabling the catalytic hydrophosphination of unactivated internal alkynes. Catalytic and stoichiometric experiments support a mechanism involving reactive Th–NHC metallacycle intermediates (Int and 2)." @default.
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• W2754040742 date "2017-09-11" @default.
• W2754040742 modified "2023-10-03" @default.
• W2754040742 title "Thorium Metallacycle Facilitates Catalytic Alkyne Hydrophosphination" @default.
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• W2754040742 doi "https://doi.org/10.1021/jacs.7b08323" @default.
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