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• W2754073181 abstract "ABSTRACT Poly{2,6‐bis(thiophene‐2‐yl)‐4,8‐bis(5‐dodecylthiophen‐2‐yl)benzo[1,2‐ b :4,5‐ b' ]dithiophene} [poly(Th‐bDTBDT‐Th)] was successfully synthesized through Stille coupling polymerization. The addition of the thiophene spacer groups between the benzodithiophene units resulted in improved performance in optoelectronic devices. This was attributed to the reduced lamellae stacking distance in thin film with prominent π–π stacking peak indicating close assembly of poly(Th‐bDTBDT‐Th). Spacing between the benzodithiophene units in poly(Th‐bDTBDT‐Th) helped the close packing of dodecyl chains and generated improved π stacking interaction. For poly(Th‐bDTBDT‐Th), the measured average field effect mobility was 2.32 × 10 −3 cm 2 V −1 s −1 and average hole mobility in vertical direction was 2.92 × 10 −5 cm 2 V −1 s −1 . Charge transport in both directions was improved by one order of magnitude with the presence of the thiophene spacer. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55 , 3942–3948" @default.
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• W2754073181 date "2017-09-15" @default.
• W2754073181 modified "2023-10-01" @default.
• W2754073181 title "Effect of thiophene spacers in benzodithiophene‐based polymers for organic electronics" @default.
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• W2754073181 doi "https://doi.org/10.1002/pola.28781" @default.
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