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- W2754140446 abstract "ABSTRACTIn an effort to synthesise thermally stable bent-core nematogens with fairly low transition temperatures and wide nematic mesophase range, we have synthesised five new series of azo-substituted bent-core compounds without Schiff’s base unit. Here, we studied the effect of different lateral substituents (–CH3 and –Cl), at two different positions in one of the arms, on the mesogenic properties. We found that such variation in the molecular architecture has a clear-cut impact on the transition temperatures as well as the liquid crystalline properties. The mesogenic properties of these compounds were studied using polarising optical microscopy and differential scanning calorimetry. The exact nature of different mesophases is investigated using X-ray diffraction studies. The results obtained indicated the presence of smectic nano clusters in the nematic mesophases of these compounds. We observed domains of opposite handedness in these nematic phases. The unusual properties of these mesophases were inve..." @default.
- W2754140446 created "2017-09-25" @default.
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- W2754140446 date "2017-09-12" @default.
- W2754140446 modified "2023-10-16" @default.
- W2754140446 title "Thermally stable azo-substituted bent-core nematogens: observation of chiral domains in the nematic mesophases composed of smectic nano clusters" @default.
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- W2754140446 doi "https://doi.org/10.1080/02678292.2017.1371344" @default.
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