FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2754185969> ?p ?o ?g. }

• W2754185969 endingPage "11651" @default.
• W2754185969 startingPage "11643" @default.
• W2754185969 abstract "Vanadium(V) is an emerging contaminant in the most recent Environmental Protection Agency's candidate contaminant list (CCL4). The redox chemistry of vanadium controls its occurrence in the aquatic environment, but the impact of vanadium(V) speciation on the redox properties remains largely unknown. This study utilized the rotating ring-disk electrode technique to examine the reduction kinetics of four pH- and concentration-dependent vanadium(V) species in the presence and the absence of phosphate. Results showed that the reduction of VO2+, HxV4O12+x(4+x)- (V4), and HVO42- proceeded via a one-electron transfer, while that of NaxHyV10O28(6-x-y)- (V10) underwent a two-electron transfer. Koutecky-Levich and Tafel analyses showed that the intrinsic reduction rate constants followed the order of V10 > VO2+ > V4 > HVO42-. Ring-electrode collection efficiency indicated that the reduction product of V10 was stable, while those of VO2+, HVO42-, and V4 had short half-lives that ranged from milliseconds to seconds. With molar ratios of phosphate to vanadium(V) varying from 0 to 1, phosphate accelerated the reduction kinetics of V10 and V4 and enhanced the stability of the reduction products of VO2+, V4, and HVO42-. This study suggests that phosphate complexation could enhance the reductive removal of vanadium(V) and inhibit the reoxidation of its reduction product in water treatment." @default.
• W2754185969 created "2017-09-25" @default.
• W2754185969 creator A5019421112 @default.
• W2754185969 creator A5064665869 @default.
• W2754185969 date "2017-09-27" @default.
• W2754185969 modified "2023-10-17" @default.
• W2754185969 title "Understanding the Reduction Kinetics of Aqueous Vanadium(V) and Transformation Products Using Rotating Ring-Disk Electrodes" @default.
• W2754185969 cites W1870914889 @default.
• W2754185969 cites W1963477449 @default.
• W2754185969 cites W1972385902 @default.
• W2754185969 cites W1981058736 @default.
• W2754185969 cites W1981829001 @default.
• W2754185969 cites W1982558069 @default.
• W2754185969 cites W1991748329 @default.
• W2754185969 cites W1997529717 @default.
• W2754185969 cites W1998331318 @default.
• W2754185969 cites W2010583888 @default.
• W2754185969 cites W2023629097 @default.
• W2754185969 cites W2031983719 @default.
• W2754185969 cites W2038210982 @default.
• W2754185969 cites W2039297284 @default.
• W2754185969 cites W2043740662 @default.
• W2754185969 cites W2045443848 @default.
• W2754185969 cites W2053137298 @default.
• W2754185969 cites W2068045334 @default.
• W2754185969 cites W2071157724 @default.
• W2754185969 cites W2071343873 @default.
• W2754185969 cites W2071893453 @default.
• W2754185969 cites W2073875289 @default.
• W2754185969 cites W2074003584 @default.
• W2754185969 cites W2078772463 @default.
• W2754185969 cites W2082410615 @default.
• W2754185969 cites W2084550375 @default.
• W2754185969 cites W2086997985 @default.
• W2754185969 cites W2090691537 @default.
• W2754185969 cites W2098957827 @default.
• W2754185969 cites W2129658004 @default.
• W2754185969 cites W2160216319 @default.
• W2754185969 cites W2165657679 @default.
• W2754185969 cites W2167302582 @default.
• W2754185969 cites W2286491730 @default.
• W2754185969 cites W2322241610 @default.
• W2754185969 cites W2327132051 @default.
• W2754185969 cites W2570191597 @default.
• W2754185969 cites W73849119 @default.
• W2754185969 doi "https://doi.org/10.1021/acs.est.7b02021" @default.
• W2754185969 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28902987" @default.
• W2754185969 hasPublicationYear "2017" @default.
• W2754185969 type Work @default.
• W2754185969 sameAs 2754185969 @default.
• W2754185969 citedByCount "60" @default.
• W2754185969 countsByYear W27541859692018 @default.
• W2754185969 countsByYear W27541859692019 @default.
• W2754185969 countsByYear W27541859692020 @default.
• W2754185969 countsByYear W27541859692021 @default.
• W2754185969 countsByYear W27541859692022 @default.
• W2754185969 countsByYear W27541859692023 @default.
• W2754185969 crossrefType "journal-article" @default.
• W2754185969 hasAuthorship W2754185969A5019421112 @default.
• W2754185969 hasAuthorship W2754185969A5064665869 @default.
• W2754185969 hasConcept C121332964 @default.
• W2754185969 hasConcept C123669783 @default.
• W2754185969 hasConcept C147789679 @default.
• W2754185969 hasConcept C148898269 @default.
• W2754185969 hasConcept C172404476 @default.
• W2754185969 hasConcept C17525397 @default.
• W2754185969 hasConcept C178790620 @default.
• W2754185969 hasConcept C179104552 @default.
• W2754185969 hasConcept C184651966 @default.
• W2754185969 hasConcept C185592680 @default.
• W2754185969 hasConcept C2777132085 @default.
• W2754185969 hasConcept C504678139 @default.
• W2754185969 hasConcept C52859227 @default.
• W2754185969 hasConcept C55904794 @default.
• W2754185969 hasConcept C62520636 @default.
• W2754185969 hasConcept C75473681 @default.
• W2754185969 hasConceptScore W2754185969C121332964 @default.
• W2754185969 hasConceptScore W2754185969C123669783 @default.
• W2754185969 hasConceptScore W2754185969C147789679 @default.
• W2754185969 hasConceptScore W2754185969C148898269 @default.
• W2754185969 hasConceptScore W2754185969C172404476 @default.
• W2754185969 hasConceptScore W2754185969C17525397 @default.
• W2754185969 hasConceptScore W2754185969C178790620 @default.
• W2754185969 hasConceptScore W2754185969C179104552 @default.
• W2754185969 hasConceptScore W2754185969C184651966 @default.
• W2754185969 hasConceptScore W2754185969C185592680 @default.
• W2754185969 hasConceptScore W2754185969C2777132085 @default.
• W2754185969 hasConceptScore W2754185969C504678139 @default.
• W2754185969 hasConceptScore W2754185969C52859227 @default.
• W2754185969 hasConceptScore W2754185969C55904794 @default.
• W2754185969 hasConceptScore W2754185969C62520636 @default.
• W2754185969 hasConceptScore W2754185969C75473681 @default.
• W2754185969 hasFunder F4320337390 @default.
• W2754185969 hasIssue "20" @default.
• W2754185969 hasLocation W27541859691 @default.
• W2754185969 hasLocation W27541859692 @default.
• W2754185969 hasOpenAccess W2754185969 @default.
• W2754185969 hasPrimaryLocation W27541859691 @default.

• next