Matches in SemOpenAlex for { <https://semopenalex.org/work/W2755493669> ?p ?o ?g. }
- W2755493669 endingPage "2915" @default.
- W2755493669 startingPage "2908" @default.
- W2755493669 abstract "Abstract A series of unsymmetrical (D‐A‐D 1 , D 1 ‐π‐D‐A‐D 1 , and D 1 ‐A 1 ‐D‐A 2 ‐D 1 ; A=acceptor, D=donor) and symmetrical (D 1 ‐A‐D‐A‐D 1 ) phenothiazines ( 4 b , 4 c , 4 c′ , 5 b , 5 c , 5 d , 5 d′ , 5 e , 5 e′ , 5 f , and 5 f′ ) were designed and synthesized by a [2+2] cycloaddition–electrocyclic ring‐opening reaction of ferrocenyl‐substituted phenothiazines with tetracyanoethylene (TCNE) and 7,7,8,8‐tetracyanoquinodimethane (TCNQ). The photophysical, electrochemical, and computational studies show a strong charge‐transfer (CT) interaction in the phenothiazine derivatives that can be tuned by varying the number of TCNE/TCNQ acceptors. Phenothiazines 4 b , 4 c , 4 c′ , 5 b , 5 c , 5 d , 5 d′ , 5 e , 5 e′ , 5 f and 5 f′ show redshifted absorption in the λ =400 to 900 nm region, as a result of a low HOMO–LUMO gap, which is supported by TD‐DFT calculations. The electrochemical study exhibits reduction waves at low potential due to strong 1,1,4,4‐tetracyanobuta‐1,3‐diene (TCBD) and cyclohexa‐2,5‐diene‐1,4‐ylidene‐expanded TCBD acceptors. The incorporation of cyclohexa‐2,5‐diene‐1,4‐ylidene‐expanded TCBD stabilized the LUMO energy level to a greater extent than TCBD." @default.
- W2755493669 created "2017-09-25" @default.
- W2755493669 creator A5004707052 @default.
- W2755493669 creator A5081181437 @default.
- W2755493669 date "2017-10-18" @default.
- W2755493669 modified "2023-10-16" @default.
- W2755493669 title "NIR‐Absorbing Donor–Acceptor Based 1,1,4,4‐Tetracyanobuta‐1,3‐Diene (TCBD)‐ and Cyclohexa‐2,5‐Diene‐1,4‐Ylidene‐Expanded TCBD‐Substituted Ferrocenyl Phenothiazines" @default.
- W2755493669 cites W1615315787 @default.
- W2755493669 cites W1965756876 @default.
- W2755493669 cites W1966632230 @default.
- W2755493669 cites W1966641110 @default.
- W2755493669 cites W1968250949 @default.
- W2755493669 cites W1968548012 @default.
- W2755493669 cites W1969055356 @default.
- W2755493669 cites W1973982428 @default.
- W2755493669 cites W1982424801 @default.
- W2755493669 cites W1983249112 @default.
- W2755493669 cites W1986931080 @default.
- W2755493669 cites W1990129926 @default.
- W2755493669 cites W1990395998 @default.
- W2755493669 cites W1995892579 @default.
- W2755493669 cites W1998312123 @default.
- W2755493669 cites W1998321559 @default.
- W2755493669 cites W1999289445 @default.
- W2755493669 cites W2009482329 @default.
- W2755493669 cites W2017475770 @default.
- W2755493669 cites W2018099531 @default.
- W2755493669 cites W2019755032 @default.
- W2755493669 cites W2027917720 @default.
- W2755493669 cites W2029838815 @default.
- W2755493669 cites W2032877759 @default.
- W2755493669 cites W2033283402 @default.
- W2755493669 cites W2041794913 @default.
- W2755493669 cites W2042816178 @default.
- W2755493669 cites W2046898448 @default.
- W2755493669 cites W2051369078 @default.
- W2755493669 cites W2055256214 @default.
- W2755493669 cites W2057370557 @default.
- W2755493669 cites W2059271574 @default.
- W2755493669 cites W2063379768 @default.
- W2755493669 cites W2064116191 @default.
- W2755493669 cites W2065028389 @default.
- W2755493669 cites W2071376734 @default.
- W2755493669 cites W2072311418 @default.
- W2755493669 cites W2073241085 @default.
- W2755493669 cites W2086927516 @default.
- W2755493669 cites W2086993799 @default.
- W2755493669 cites W2089033502 @default.
- W2755493669 cites W2089633369 @default.
- W2755493669 cites W2089665576 @default.
- W2755493669 cites W2090084145 @default.
- W2755493669 cites W2091688865 @default.
- W2755493669 cites W2093690374 @default.
- W2755493669 cites W2094271182 @default.
- W2755493669 cites W2096867598 @default.
- W2755493669 cites W2109400248 @default.
- W2755493669 cites W2118145503 @default.
- W2755493669 cites W2128826392 @default.
- W2755493669 cites W2171094221 @default.
- W2755493669 cites W2171559455 @default.
- W2755493669 cites W2190461992 @default.
- W2755493669 cites W2194125514 @default.
- W2755493669 cites W2285183139 @default.
- W2755493669 cites W2287689952 @default.
- W2755493669 cites W2312481731 @default.
- W2755493669 cites W2316468890 @default.
- W2755493669 cites W2319521699 @default.
- W2755493669 cites W2330089638 @default.
- W2755493669 cites W2330134822 @default.
- W2755493669 cites W2330645035 @default.
- W2755493669 cites W2333409015 @default.
- W2755493669 cites W2550049582 @default.
- W2755493669 cites W2618954539 @default.
- W2755493669 cites W2621806037 @default.
- W2755493669 cites W2951430167 @default.
- W2755493669 cites W2951964579 @default.
- W2755493669 cites W2952926322 @default.
- W2755493669 cites W4213212961 @default.
- W2755493669 cites W4236892148 @default.
- W2755493669 doi "https://doi.org/10.1002/asia.201700879" @default.
- W2755493669 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28901716" @default.
- W2755493669 hasPublicationYear "2017" @default.
- W2755493669 type Work @default.
- W2755493669 sameAs 2755493669 @default.
- W2755493669 citedByCount "15" @default.
- W2755493669 countsByYear W27554936692018 @default.
- W2755493669 countsByYear W27554936692020 @default.
- W2755493669 countsByYear W27554936692021 @default.
- W2755493669 countsByYear W27554936692022 @default.
- W2755493669 countsByYear W27554936692023 @default.
- W2755493669 crossrefType "journal-article" @default.
- W2755493669 hasAuthorship W2755493669A5004707052 @default.
- W2755493669 hasAuthorship W2755493669A5081181437 @default.
- W2755493669 hasConcept C121332964 @default.
- W2755493669 hasConcept C14158195 @default.
- W2755493669 hasConcept C147789679 @default.
- W2755493669 hasConcept C161790260 @default.
- W2755493669 hasConcept C17525397 @default.