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- W2756039461 abstract "Abstract A series of diabolo‐like nonanuclear {Ln III Cu II 8 } (Ln=Tb, Dy, Ho, Er, Tm, Yb, and Y) clusters were prepared in which the Ln III ion is capped by two 8‐MC‐4 metallacrown ligands to form a nearly ideal square antiprismatic (SAP) coordination geometry with D 4 d symmetry. Despite the lack of crystallographic symmetry, these molecules engender the lanthanide ions with highly axial m J states. The axial/equatorial nature of the crystal field in environments close to ideal SAP geometry is very subtle and influenced by the nature of the ligand lone pairs. Slow magnetic relaxation behaviour was observed for the Dy III , Er III , Tm III , and Yb III analogues, and the obtained effective energy barriers are not consistent with excitations on the Ln III ion, suggesting a more nuanced situation." @default.
- W2756039461 created "2017-09-25" @default.
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- W2756039461 date "2017-10-13" @default.
- W2756039461 modified "2023-10-14" @default.
- W2756039461 title "Metallacrowns as Templates for Diabolo-like {LnCu<sub>8</sub> } Complexes with Nearly Perfect Square Antiprismatic Geometry" @default.
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- W2756039461 doi "https://doi.org/10.1002/chem.201703830" @default.
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