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• W2756561412 endingPage "10957" @default.
• W2756561412 startingPage "10951" @default.
• W2756561412 abstract "In mixtures of water and dimethyl sulfoxide, 4′-(n-dodecyloxy)-1,1′-biphenyl-4-carbonyl Ala–Ala dipeptides can self-assemble into tubular structures that are formed by coiled nanoribbons. The twist and stacking handedness of biphenylene groups were studied using circular dichroism and confirmed by theoretical chemical calculations. The handedness of the coiled nanoribbons and the stacking handedness of biphenylene groups are controlled by the chirality of alanine at the C-terminus, whereas the twist handedness of biphenylene groups is determined by the chirality of alanine at the N-terminus. 1H NMR spectra indicated that the hydrogen bond formed by the N–H group of alanine at the N-terminus plays an important role in the formation of organic self-assemblies. On the basis of small-angle X-ray scattering characterization, a dimer structure was proposed to form through the terminal COOH groups." @default.
• W2756561412 created "2017-10-06" @default.
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• W2756561412 date "2017-10-04" @default.
• W2756561412 modified "2023-10-17" @default.
• W2756561412 title "Aggregation-Induced Chirality: Twist and Stacking Handedness of the Biphenylene Groups of <i>n</i>-C₁₂H₂₅O-BP-CO-Ala-Ala Dipeptides" @default.
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• W2756561412 doi "https://doi.org/10.1021/acs.langmuir.7b02576" @default.
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• W2756561412 hasPublicationYear "2017" @default.
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