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• W2756664912 abstract "Cobalt-catalyzed selective α-alkylation and α-heteroarylation processes of α-amino esters and peptide derivatives are described. These cross-dehydrogenative reactions occur under mild conditions and allow for the rapid assembly of structurally diverse α-amino carbonyl compounds. Unlike enolate chemistry, these methods are distinguished by their site-specificity, occur without racemization of the existing chiral centers, and exhibit total selectivity for aryl glycine motifs over other amino acid units, hence providing ample opportunities for peptide modifications." @default.
• W2756664912 created "2017-10-06" @default.
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• W2756664912 date "2017-09-22" @default.
• W2756664912 modified "2023-10-17" @default.
• W2756664912 title "Co-Catalyzed C(sp³)–H Oxidative Coupling of Glycine and Peptide Derivatives" @default.
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• W2756664912 doi "https://doi.org/10.1021/acs.orglett.7b02567" @default.
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