Matches in SemOpenAlex for { <https://semopenalex.org/work/W2757103680> ?p ?o ?g. }
- W2757103680 endingPage "485" @default.
- W2757103680 startingPage "482" @default.
- W2757103680 abstract "The accurate potentials of Ph2I+ cation reduction, yielding in one step Ph• and PhI, are equal to −0.68, −0.61 and −0.67 V vs. SCE, in MeCN, DMF and water, respectively, according to state-of-the-art quantum chemical calculations using the benchmark gas-phase energetics (the C–I bond homolytic dissociation energy in Ph2I+ and electron affinity of PhI•+) from the explicitly correlated coupled-cluster method (CCSD(T)-F12) together with the SMD solvation free energies. The alkyl (Me or t‐Bu) substitution effect on the reduction potential of Ph2I+ was estimated to be less than 50 mV. It was demonstrated that employing the ubiquitously used erroneous E°(Ph2I+) value of −0.2 V in the prediction of ΔG° for photoinduced electron transfer may lead to failed photoinitiated polymerisation experiments." @default.
- W2757103680 created "2017-10-06" @default.
- W2757103680 creator A5091618211 @default.
- W2757103680 creator A5012913880 @default.
- W2757103680 date "2017-11-01" @default.
- W2757103680 modified "2023-10-18" @default.
- W2757103680 title "The Reduction Potential of Diphenyliodonium Polymerisation Photoinitiator Is Not −0.2 V vs. SCE. A Computational Study" @default.
- W2757103680 cites W150731749 @default.
- W2757103680 cites W1792295936 @default.
- W2757103680 cites W1986386367 @default.
- W2757103680 cites W1991647825 @default.
- W2757103680 cites W1995945917 @default.
- W2757103680 cites W1998970054 @default.
- W2757103680 cites W2000193505 @default.
- W2757103680 cites W2009452151 @default.
- W2757103680 cites W2011215428 @default.
- W2757103680 cites W2017339391 @default.
- W2757103680 cites W2021770275 @default.
- W2757103680 cites W2024744001 @default.
- W2757103680 cites W2029606458 @default.
- W2757103680 cites W2038680753 @default.
- W2757103680 cites W2057955594 @default.
- W2757103680 cites W2063074480 @default.
- W2757103680 cites W2065205990 @default.
- W2757103680 cites W2076867847 @default.
- W2757103680 cites W2092157292 @default.
- W2757103680 cites W2129126460 @default.
- W2757103680 cites W2235741941 @default.
- W2757103680 cites W2335628838 @default.
- W2757103680 cites W2475311614 @default.
- W2757103680 cites W2522180034 @default.
- W2757103680 cites W2551726330 @default.
- W2757103680 cites W2551813627 @default.
- W2757103680 cites W2572449726 @default.
- W2757103680 cites W2594855412 @default.
- W2757103680 cites W4244504246 @default.
- W2757103680 doi "https://doi.org/10.1016/j.electacta.2017.09.166" @default.
- W2757103680 hasPublicationYear "2017" @default.
- W2757103680 type Work @default.
- W2757103680 sameAs 2757103680 @default.
- W2757103680 citedByCount "49" @default.
- W2757103680 countsByYear W27571036802018 @default.
- W2757103680 countsByYear W27571036802019 @default.
- W2757103680 countsByYear W27571036802020 @default.
- W2757103680 countsByYear W27571036802021 @default.
- W2757103680 countsByYear W27571036802022 @default.
- W2757103680 countsByYear W27571036802023 @default.
- W2757103680 crossrefType "journal-article" @default.
- W2757103680 hasAuthorship W2757103680A5012913880 @default.
- W2757103680 hasAuthorship W2757103680A5091618211 @default.
- W2757103680 hasConcept C102931765 @default.
- W2757103680 hasConcept C123669783 @default.
- W2757103680 hasConcept C139066938 @default.
- W2757103680 hasConcept C145148216 @default.
- W2757103680 hasConcept C147597530 @default.
- W2757103680 hasConcept C147789679 @default.
- W2757103680 hasConcept C148093993 @default.
- W2757103680 hasConcept C166940927 @default.
- W2757103680 hasConcept C175689099 @default.
- W2757103680 hasConcept C178790620 @default.
- W2757103680 hasConcept C185592680 @default.
- W2757103680 hasConcept C2780634384 @default.
- W2757103680 hasConcept C2781238429 @default.
- W2757103680 hasConcept C32909587 @default.
- W2757103680 hasConcept C521977710 @default.
- W2757103680 hasConcept C62396407 @default.
- W2757103680 hasConcept C75473681 @default.
- W2757103680 hasConceptScore W2757103680C102931765 @default.
- W2757103680 hasConceptScore W2757103680C123669783 @default.
- W2757103680 hasConceptScore W2757103680C139066938 @default.
- W2757103680 hasConceptScore W2757103680C145148216 @default.
- W2757103680 hasConceptScore W2757103680C147597530 @default.
- W2757103680 hasConceptScore W2757103680C147789679 @default.
- W2757103680 hasConceptScore W2757103680C148093993 @default.
- W2757103680 hasConceptScore W2757103680C166940927 @default.
- W2757103680 hasConceptScore W2757103680C175689099 @default.
- W2757103680 hasConceptScore W2757103680C178790620 @default.
- W2757103680 hasConceptScore W2757103680C185592680 @default.
- W2757103680 hasConceptScore W2757103680C2780634384 @default.
- W2757103680 hasConceptScore W2757103680C2781238429 @default.
- W2757103680 hasConceptScore W2757103680C32909587 @default.
- W2757103680 hasConceptScore W2757103680C521977710 @default.
- W2757103680 hasConceptScore W2757103680C62396407 @default.
- W2757103680 hasConceptScore W2757103680C75473681 @default.
- W2757103680 hasFunder F4320326815 @default.
- W2757103680 hasLocation W27571036801 @default.
- W2757103680 hasOpenAccess W2757103680 @default.
- W2757103680 hasPrimaryLocation W27571036801 @default.
- W2757103680 hasRelatedWork W1968278713 @default.
- W2757103680 hasRelatedWork W1973540331 @default.
- W2757103680 hasRelatedWork W1974098929 @default.
- W2757103680 hasRelatedWork W2022854190 @default.
- W2757103680 hasRelatedWork W2024662799 @default.
- W2757103680 hasRelatedWork W2030630216 @default.
- W2757103680 hasRelatedWork W2067644274 @default.
- W2757103680 hasRelatedWork W2085646616 @default.
- W2757103680 hasRelatedWork W2314667259 @default.
- W2757103680 hasRelatedWork W2323370647 @default.