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• W2757363553 abstract "An efficient copper-catalyzed synthesis of indol-3-yl α-(difluoromethyl)-α-(trifluoromethyl)carbinols is developed. The reaction proceeds in good to excellent yields through a Friedel–Crafts-type mechanism, and a variety of indoles with commonly occurring functional groups such as formyl, cyano, nitro, alkyloxide, and halogen are well tolerated. In addition, these carbinol products are readily transformed into diversified difluoromethylated dinitrile indol-3-yl derivatives. This strategy provides a general synthetic method for ready construction of difluoromethylated sp3 carbon centers." @default.
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• W2757363553 date "2017-09-28" @default.
• W2757363553 modified "2023-10-18" @default.
• W2757363553 title "Copper-Catalyzed Synthesis of Indol-3-yl α-(Difluoromethyl)-α-(trifluoromethyl)carbinols: Construction of Difluoromethylated sp³ Carbon Centers" @default.
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• W2757363553 doi "https://doi.org/10.1021/acs.orglett.7b02828" @default.
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