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- W2757385097 abstract "The probe 1 was readily prepared via condensation of 8-formyl-7-hydroxy-coumarin and carbonic dihydrazide in a one-step procedure. Probe 1 exhibited high sensitivity and selectivity towards Zn²⁺ and F⁻ through a “turn-on” fluorescence response and/or ratiometric colorimetric response with low detection limits of the order of 10-8 M. The complex behaviour was fully investigated by spectral titration, isothermal titration calorimetry, 1H NMR spectroscopic titration and mass spectrometry. Interestingly, probe 1 not only recognizes the cation Zn²⁺ and the anion F⁻, but can also distinguish between these two ions via the max wavelength in their UV-vis spectra (360 nm for 1-Zn²⁺ versus 400 nm for 1-F⁻ complex) or their fluorescent spectra (λₑₓ / λₑm = 360 nm/ 454 nm for 1-Zn²⁺ versus λₑₓ / λₑm = 400 nm/ 475 nm for 1-F⁻ complex) due to their differing red-shifts. Additionally, probe 1 has been further explored in the detection of Zn²⁺ in living cells." @default.
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- W2757385097 date "2017-05-03" @default.
- W2757385097 modified "2023-09-22" @default.
- W2757385097 title "A readily accessible multifunctional probe: simultaneous recognition of the cation ZN²⁺ and the anion F⁻ via distinguishable wavelengths" @default.
- W2757385097 doi "https://doi.org/10.11862/cjic.2017.076" @default.
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