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- W2757890639 endingPage "14040" @default.
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- W2757890639 abstract "The new iron(IV) nitride complex PhB(iPr2Im)3Fe≡N reacts with 2 equiv of bis(diisopropylamino)cyclopropenylidene (BAC) to provide PhB(iPr2Im)3Fe(CN)(N2)(BAC). This unusual example of a four-electron reaction involves carbon atom transfer from BAC to create a cyanide ligand along with the alkyne iPr2N–C≡C–NiPr2. The iron complex is in equilibrium with an N2-free species. Further reaction with CO leads to formation of a CO analogue, which can be independently prepared using NaCN as the cyanide source, while reaction with B(C6F5)3 provides the cyanoborane derivative." @default.
- W2757890639 created "2017-10-06" @default.
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- W2757890639 date "2017-09-26" @default.
- W2757890639 modified "2023-10-15" @default.
- W2757890639 title "Cyanide Ligand Assembly by Carbon Atom Transfer to an Iron Nitride" @default.
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- W2757890639 doi "https://doi.org/10.1021/jacs.7b08704" @default.
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