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• W2758003485 abstract "The ability to trap adatoms with an organic molecule on a surface has been used to obtain a range of molecular functionalities controlled by the choice of the molecular trapping site and local deprotonation. The tetraphenylporphyrin molecule used in this study contains three types of trapping sites: two carbon rings (phenyl and pyrrole) and the center of a macrocycle. Catching a gold adatom on the carbon rings leads to an electronic doping of the molecule, whereas trapping the adatom at the macrocycle center with single deprotonation leads to a molecular rotor and a second deprotonation leads to a molecular jumper. We call atom trapping chemistry the control of the structure, electronic, and dynamical properties of a molecule achieved by trapping metallic atoms with a molecule on a surface. In addition to the examples previously described, we show that more complex structures can be envisaged." @default.
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• W2758003485 date "2017-10-05" @default.
• W2758003485 modified "2023-10-18" @default.
• W2758003485 title "Tuning the Electronic and Dynamical Properties of a Molecule by Atom Trapping Chemistry" @default.
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• W2758003485 doi "https://doi.org/10.1021/acsnano.7b05235" @default.
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