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• W2758163599 abstract "Abstract Copper-substituted calcium in hydroxyapatite nanocrystals (CuHAp) were synthesized by co-precipitation method and characterized using various analyses. Structural and chemical characterizations indicate that copper was quantitatively incorporated into the HAp structure, replacing calcium up to 15 at.%. The presence of copper in the HAp structure affected clearly its crystallinity and reduced its crystallite sizes. Rietveld analysis showed a regular decrease of the CuHAp cell parameters a and c. Moreover, this substitution caused a shift in the infrared absorption bands and the nuclear magnetic resonance signals of phosphate groups and a decrease in the thermal stability. Morphological characterizations indicated that the prepared CuHAp consists of extremely thin needle-shaped nanocrystals with a greater aggregation, and confirmed the decrease in crystal size that was associated to the increasing in the surface area. The prepared CuHAp nanocrystals showed a high catalytic effect (up to 70%) in the discoloration of the Naphthol Blue Black solutions." @default.
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• W2758163599 date "2018-01-01" @default.
• W2758163599 modified "2023-10-17" @default.
• W2758163599 title "Synthesis, characterization and catalytic properties of copper-substituted hydroxyapatite nanocrystals" @default.
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• W2758163599 doi "https://doi.org/10.1016/j.materresbull.2017.09.056" @default.
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