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- W2758589600 endingPage "14052" @default.
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- W2758589600 abstract "We report a Rh-catalyzed hydroamination of 1,3-dienes to generate homoallylic amines. Our work showcases the first case of anti-Markovnikov selectivity in the intermolecular coupling of amines and 1,3-dienes. By tuning the ligand properties and Brønsted acid additive, we find that a combination of rac-BINAP and mandelic acid is critical for achieving anti-Markovnikov selectivity." @default.
- W2758589600 created "2017-10-06" @default.
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- W2758589600 date "2017-09-27" @default.
- W2758589600 modified "2023-10-18" @default.
- W2758589600 title "Intermolecular Hydroamination of 1,3-Dienes To Generate Homoallylic Amines" @default.
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- W2758589600 doi "https://doi.org/10.1021/jacs.7b09188" @default.
- W2758589600 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6563820" @default.
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