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- W2759093416 abstract "Abstract The peculiar architectures consisting of electrospun carbon nanofibers coaxially decorated by porous worm-like NiMoO 4 were successfully fabricated for the first time to address the poor cycling stability and inferior rate capability of the state-of-the-art NiMoO 4 -based electrodes caused by the insufficient structural stability, dense structure and low conductivity. The porous worm-like structure endows the electrode high capacitance/capacity due to large effective specific surface area and short electron/ion diffusion channels. Moreover, the robust integrated electrode with sufficient internal spaces can self-accommodate volume variation during charge/discharge processes, which is beneficial to the structural stability and integrity. By the virtue of rational design of the architecture, the hybrid electrode delivered high specific capacitance (1088.5 F g −1 at 1 A g −1 ), good rate capability (860.3 F g −1 at 20 A g −1 ) and long lifespan with a capacitance retention of 73.9% after 5000 cycles when used as supercapacitor electrode. For lithium-ion battery application, the electrode exhibited a high reversible capacity of 1132.1 mAh g −1 at 0.5 A g −1 . Notably, 689.7 mAh g −1 can be achieved even after 150 continuous cycles at a current density of 1 A g −1 . In the view of their outstanding electrochemical performance and the cost-effective fabrication process, the integrated nanostructure shows great promising applications in energy storage." @default.
- W2759093416 created "2017-10-06" @default.
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- W2759093416 date "2018-03-01" @default.
- W2759093416 modified "2023-09-28" @default.
- W2759093416 title "Porous worm-like NiMoO4 coaxially decorated electrospun carbon nanofiber as binder-free electrodes for high performance supercapacitors and lithium-ion batteries" @default.
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- W2759093416 doi "https://doi.org/10.1016/j.apsusc.2017.09.153" @default.
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