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- W2759094951 abstract "We propose a definition of the effective hard-sphere volume fraction (phi_HS) for liquids composed of soft repulsive particles by employing the condition of compressibility equivalence, and devise a model-independent method to determine phi_HS for soft colloids from Small-Angle Neutron Scattering (SANS) experiments. A series of star polymer dispersions are measured as a model soft colloidal liquid. It is found that as the concentration increases, the slowing of the long-time dynamics of the star polymer, normalized by the short-time self-diffusion coefficient, can be scaled to the hard-sphere behavior with phi_HS. This result agrees with the dynamic equivalence rule between the soft-repulsive and hard-sphere colloidal liquids predicted by recent theoretical and simulation work." @default.
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- W2759094951 date "2017-09-24" @default.
- W2759094951 modified "2023-09-24" @default.
- W2759094951 title "Observation of the Dynamic Equivalence between Soft Star Polymers and Hard Spheres via Compressibility Scaling" @default.
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