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- W2759103427 endingPage "11976" @default.
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- W2759103427 abstract "In this study, a high-flux organic solvent nanofiltration (OSN) membrane with the permeance of 66.7 Lm–2 h–1 bar–1 in methanol and 38.0 Lm–2 h–1 bar–1 in ethanol was successfully prepared from nanoporous PAN by phase inversion and hydrolyzation in sodium hydroxide solution. The polymer concentration and hydrolysis time were varied to control the final morphology and performance. The ternary phase diagram and viscosity measurements were used to describe precipitation thermodynamics and kinetics of the phase inversion process. The prepared membranes had a typical asymmetric structure, which could be observed from images of the cross section, comprising a dense skin layer and a porous substructure in the sublayer. It was found that the polymer concentration has an apparent influence on the morphology, selectivity and permeability of the prepared membranes. FTIR analysis, ζ-potential and water contact angle measurements confirm a molecular chain rearrangement as hydrogen bonds were formed between CONH2 and CO..." @default.
- W2759103427 created "2017-10-06" @default.
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- W2759103427 date "2017-10-09" @default.
- W2759103427 modified "2023-09-23" @default.
- W2759103427 title "Preparation of High-Flux Nanoporous Solvent Resistant Polyacrylonitrile Membrane with Potential Fractionation of Dyes and Na<sub>2</sub>SO<sub>4</sub>" @default.
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- W2759103427 doi "https://doi.org/10.1021/acs.iecr.7b03409" @default.
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